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N-cinnamoylanthranilates as human TRPA1 modulators: Structure-activity relationships and channel binding sites (2019)
Journal Article
Chandrabalan, A., McPhillie, M. J., Morice, A. H., Boa, A. N., & Sadofsky, L. R. (2019). N-cinnamoylanthranilates as human TRPA1 modulators: Structure-activity relationships and channel binding sites. European Journal of Medicinal Chemistry, 170, 141-156. https://doi.org/10.1016/j.ejmech.2019.02.074

The transient receptor potential ankyrin 1 (TRPA1) channel is a non-selective cation channel, which detects noxious stimuli leading to pain, itch and cough. However, the mechanism(s) of channel modulation by many of the known, non-reactive modulators... Read More about N-cinnamoylanthranilates as human TRPA1 modulators: Structure-activity relationships and channel binding sites.

Tetraazamacrocyclic derivatives and their metal complexes as antileishmanial leads (2019)
Journal Article
Hubin, T. J., Walker, A. N., Davilla, D. J., Carder Freeman, T. R. N., Epley, B. M., Hasley, T. R., Amoyaw, P. N., Jain, S., Archibald, S. J., Prior, T. J., Krause, J. A., Oliver, A. G., Tekwani, B. L., & Khan, M. O. F. (2019). Tetraazamacrocyclic derivatives and their metal complexes as antileishmanial leads. Polyhedron, 163, 42-53. https://doi.org/10.1016/j.poly.2019.02.027

© 2019 A total of 44 bis-aryl-monocyclic polyamines, monoaryl-monocyclic polyamines and their transition metal complexes were prepared, chemically characterized, and screened in vitro against the Leishmania donovani promastigotes, axenic amastigotes... Read More about Tetraazamacrocyclic derivatives and their metal complexes as antileishmanial leads.

The inhibitory subunit of cardiac troponin (cTnI) is modified by arginine methylation in the human heart (2019)
Journal Article
Onwuli, D. O., Samuel, S., Sfyri, P., Welham, K., Goddard, M., Abu-Omar, Y., Loubani, M., Rivero, F., Matsakas, A., Benoit, D. M., Wade, M., Greenman, J., & Beltran-Alvarez, P. (2019). The inhibitory subunit of cardiac troponin (cTnI) is modified by arginine methylation in the human heart. International journal of cardiology, 282, 76-80. https://doi.org/10.1016/j.ijcard.2019.01.102

Background The inhibitory subunit of cardiac troponin (cTnI) is a gold standard cardiac biomarker and also an essential protein in cardiomyocyte excitation-contraction coupling. The interactions of cTnI with other proteins are fine-tuned by post-tra... Read More about The inhibitory subunit of cardiac troponin (cTnI) is modified by arginine methylation in the human heart.

1H NMR study of molecular order and dynamics in the liquid crystal CB-C9-CB (2019)
Journal Article
Aluculesei, A., Cachitas, H., Carvalho, J., Vaca Chavez, F., Figueirinhas, J. L., Sebastião, P. J., Cruz, C., Tamba, M. G., Kohlemeir, A., & Mehl, G. H. (2019). 1H NMR study of molecular order and dynamics in the liquid crystal CB-C9-CB. Physical chemistry chemical physics : PCCP, 21(8), 4523-4537. https://doi.org/10.1039/c8cp06868b

© 2019 the Owner Societies. Molecular order and dynamics of the CB-C9-CB liquid crystalline dimer exhibiting the nematic (N) and the twist bend nematic (Ntb) phases were investigated by proton NMR spectroscopy, using fields of 0.78 T and 7.04 T, and... Read More about 1H NMR study of molecular order and dynamics in the liquid crystal CB-C9-CB.

Acetate as a model for aspartate-based CXCR4 chemokine receptor binding of cobalt and nickel complexes of cross-bridged tetraazamacrocycles (2019)
Journal Article
Cain, A. N., Carder Freeman, T. N., Roewe, K. D., Cockriel, D. L., Hasley, T. R., Maples, R. D., Allbritton, E. M. A., D'Huys, T., van Loy, T., Burke, B. P., Prior, T. J., Schols, D., Archibald, S. J., & Hubin, T. J. (2019). Acetate as a model for aspartate-based CXCR4 chemokine receptor binding of cobalt and nickel complexes of cross-bridged tetraazamacrocycles. Dalton Transactions : an international journal of inorganic chemistry, 48(8), 2785-2801. https://doi.org/10.1039/c8dt04728f

A number of disease states including WHIM syndrome, HIV infection and cancer have been linked to the chemokine receptor CXCR4. High-affinity CXCR4 antagonist transition metal complexes of configurationally restricted bis-tetraazamacrocyclic ligands h... Read More about Acetate as a model for aspartate-based CXCR4 chemokine receptor binding of cobalt and nickel complexes of cross-bridged tetraazamacrocycles.

Pickering emulsion-enhanced interfacial biocatalysis: tailored alginate microparticles act as particulate emulsifier and enzyme carrier (2019)
Journal Article
Yang, X., Wang, Y., Bai, R., Ma, H., Wang, W., Sun, H., Dong, Y., Qu, F., Tang, Q., Guo, T., Binks, B. P., & Meng, T. (2019). Pickering emulsion-enhanced interfacial biocatalysis: tailored alginate microparticles act as particulate emulsifier and enzyme carrier. Green chemistry : an international journal and green chemistry resource : GC, 21(9), 2229-2233. https://doi.org/10.1039/c8gc03573c

A robust Pickering emulsion stabilized by lipase-immobilized alginate gel microparticles with a coating of silanized titania nanoparticles is developed for biphasic biocatalysis. The good recyclability and high stability of the proposed interfacial c... Read More about Pickering emulsion-enhanced interfacial biocatalysis: tailored alginate microparticles act as particulate emulsifier and enzyme carrier.

Stereolithographic 3D printing of extrinsically self-healing composites (2019)
Journal Article
Sanders, P., Young, A. J., Qin, Y., Fancey, K. S., Reithofer, M. R., Guillet-Nicolas, R., Kleitz, F., Pamme, N., & Chin, J. M. (2019). Stereolithographic 3D printing of extrinsically self-healing composites. Scientific reports, 9(1), Article 388. https://doi.org/10.1038/s41598-018-36828-9

We demonstrate for the first time the direct stereolithographic 3D printing of an extrinsically self-healing composite, comprised of commercial photocurable resin modified with anisole and PMMA-filled microcapsules. The composites demonstrate solvent... Read More about Stereolithographic 3D printing of extrinsically self-healing composites.

Proton and Deuterium NMR study of the CBC9CB Dimer System (2019)
Journal Article
Carvalho, J., Cruz, C., Figueirinhas, J. L., Tamba, M.-G., Kohlmeier, A., & Mehl, G. H. (2019). Proton and Deuterium NMR study of the CBC9CB Dimer System. Journal of Physical Chemistry B, 123(6), 1442-1451. https://doi.org/10.1021/acs.jpcb.8b11526

Copyright © 2019 American Chemical Society. Using proton and deuterium NMR spectroscopy, this work provides a description of the molecular orientational order of the mesogenic groups in both the N tb and the classical nematic phase (N) of the liquid... Read More about Proton and Deuterium NMR study of the CBC9CB Dimer System.

Pyrene-based blue emitters with aggregation-induced emission features for high-performance organic light-emitting diodes (2019)
Journal Article
Feng, X., Xu, Z., Hu, Z., Qi, C., Luo, D., Zhao, X., Mu, Z., Lam, J. W. Y., Redshaw, C., Ma, D., & Tang, B. Z. (2019). Pyrene-based blue emitters with aggregation-induced emission features for high-performance organic light-emitting diodes. Journal of Materials Chemistry C, 7(8), 2283-2290. https://doi.org/10.1039/c8tc05547e

© 2019 The Royal Society of Chemistry. Pyrene is a representative aggregation-caused quenching (ACQ) chromophore. Herein, by introducing tetraphenylethylene or triphenylethylene with a typical aggregation-induced emission (AIE) characteristic at pyr... Read More about Pyrene-based blue emitters with aggregation-induced emission features for high-performance organic light-emitting diodes.

Crystal structure of (1,3-thiazole-2-carboxylato-κ N)(1,3-thiazole-2-carboxylic acid-κ N)silver(I) (2019)
Journal Article
Meundaeng, N., Rujiwatra, A., & Prior, T. J. (2019). Crystal structure of (1,3-thiazole-2-carboxylato-κ N)(1,3-thiazole-2-carboxylic acid-κ N)silver(I). Acta Crystallographica Section E: Crystallographic Communications, 75(2), 185-188. https://doi.org/10.1107/S2056989019000124

© Meundaeng et al. 2019. The linear two-coordinate silver (I) complex [Ag(C 4 H 2 NO 2 S)(C 4 H 3 NO 2 S)] or [Ag(2-Htza)(2-tza)] is reported (2-Htza = 1,3-thiazole-2-carboxylic acid). The Ag I ion is coordinated by two heterocyclic N atoms from two... Read More about Crystal structure of (1,3-thiazole-2-carboxylato-κ N)(1,3-thiazole-2-carboxylic acid-κ N)silver(I).

A label-free aptamer-based nanogap capacitive biosensor with greatly diminished electrode polarization effects (2019)
Journal Article
Ghobaei Namhil, Z., Kemp, C., Verrelli, E., Iles, A., Pamme, N., Adawi, A. M., & Kemp, N. (2019). A label-free aptamer-based nanogap capacitive biosensor with greatly diminished electrode polarization effects. Physical chemistry chemical physics : PCCP, 21(2), 681-691. https://doi.org/10.1039/c8cp05510f

A significant impediment to the use of impedance spectroscopy in bio-sensing is the electrode polarization effect that arises from the movement of free ions to the electrode-solution interface, forming an electrical double layer (EDL). The EDL screen... Read More about A label-free aptamer-based nanogap capacitive biosensor with greatly diminished electrode polarization effects.

Erratum: Synthesis and structure of the inclusion complex {NDQ[5]K@Q[10](H2O)4}·4NO3·20H2O. (Molecules (2017) 22 (1147) (2019)
Journal Article
Chen, L. X., Kan, J. L., Cong, H., Prior, T. J., Tao, Z., Xiao, X., & Redshaw, C. (2019). Erratum: Synthesis and structure of the inclusion complex {NDQ[5]K@Q[10](H2O)4}·4NO3·20H2O. (Molecules (2017) 22 (1147). Molecules, 24(2), Article 328. https://doi.org/10.3390/molecules24020328

© 2019 by the authors. The authors wish to make the following correction to their paper [1]: We found that in the Authorship section, below the second address, a mistake exists on the published page. The e-mail, which is stated as “juha.kiviluoma@vtt... Read More about Erratum: Synthesis and structure of the inclusion complex {NDQ[5]K@Q[10](H2O)4}·4NO3·20H2O. (Molecules (2017) 22 (1147).