Vanadium-based pro-catalysts bearing depleted 1,3-calix[4]arenes for ethylene or ε-caprolactone polymerization
(2011)
Journal Article
Clowes, L., Redshaw, C., & Hughes, D. L. (2011). Vanadium-based pro-catalysts bearing depleted 1,3-calix[4]arenes for ethylene or ε-caprolactone polymerization. Inorganic chemistry, 50(16), 7838-7845. https://doi.org/10.1021/ic2010198
Reaction of [V(X)(OR)3] (X = O, Np-tolyl, R = nPr, tBu) with 5,11,17,23-tBu-25,27-dihydroxycalix[4]arene (LH2) led to the formation of [V(X)(OR)L]2 X = O, R = nPr (1); X = Np-tolyl, R = nPr (2); X = Np-tolyl, R = tBu (3) as the major product. In the... Read More about Vanadium-based pro-catalysts bearing depleted 1,3-calix[4]arenes for ethylene or ε-caprolactone polymerization.