All Outputs (1143)

2-Benzimidazolyl-N-phenylquinoline-8-carboxamide chromium(III) trichlorides: Synthesis and application for ethylene oligomerization and polymerization (2011)
Journal Article
Wang, D., Liu, S., Zeng, Y., Sun, W. H., & Redshaw, C. (2011). 2-Benzimidazolyl-N-phenylquinoline-8-carboxamide chromium(III) trichlorides: Synthesis and application for ethylene oligomerization and polymerization. Organometallics, 30(11), 3001-3009. https://doi.org/10.1021/om2001124

A series of chromium(III) complexes, LCrCl3 (C1-C6: L = 2-(1H-benzo- [d]imidazol-2-yl)-N-(2,6-R1-4-R2-phenyl) quinoline-8-carboxamide; C1: R1 = iPr, R2 = H; C2: R1 = Et, R2= H; C3: R1 = Me, R2 = H; C4: R1 = Me, R2 = Me; C5: R1 = H, R2 = H; C6: R 1 =... Read More about 2-Benzimidazolyl-N-phenylquinoline-8-carboxamide chromium(III) trichlorides: Synthesis and application for ethylene oligomerization and polymerization.

Helimeric porphyrinoids: Stereostructure and chiral resolution of meso -tetraarylmorpholinochlorins (2011)
Journal Article
Brückner, C., Götz, D. C. G., Fox, S. P., Ryppa, C., McCarthy, J. R., Bruhn, T., Akhigbe, J., Banerjee, S., Daddario, P., Daniell, H. W., Zeller, M., Boyle, R. W., & Bringmann, G. (2011). Helimeric porphyrinoids: Stereostructure and chiral resolution of meso -tetraarylmorpholinochlorins. Journal of the American Chemical Society, 133(22), 8740-8752. https://doi.org/10.1021/ja202451t

The synthesis and chiral resolution of free-base and Ni(II) complexes of a number of derivatives of meso-tetraphenylmorpholinochlorins, with and without direct β-carbon-to-o-phenyl linkages to the flanking phenyl groups, is described. The morpholinoc... Read More about Helimeric porphyrinoids: Stereostructure and chiral resolution of meso -tetraarylmorpholinochlorins.

Liquid marbles stabilized by graphite particles from aqueous surfactant solutions (2011)
Journal Article
Doganci, M. D., Sesli, B. U., Erbil, H. Y., Salama, I. E., & Binks, B. P. (2011). Liquid marbles stabilized by graphite particles from aqueous surfactant solutions. Colloids and surfaces. A, Physicochemical and engineering aspects, 384(1-3), 417-426. https://doi.org/10.1016/j.colsurfa.2011.04.027

When a hydrophobic powder encapsulates a liquid drop, it forms a liquid marble which is non-wetting and behaves as a micro-reservoir of the liquid able to move without any leakage. In this work, we successfully prepared liquid marbles by encapsulatin... Read More about Liquid marbles stabilized by graphite particles from aqueous surfactant solutions.

Microsystems for personalized biomolecular diagnostics (2011)
Journal Article
Shaw, K. J., Birch, C., Hughes, E. M., Jakes, A. D., Greenman, J., & Haswell, S. J. (2011). Microsystems for personalized biomolecular diagnostics. Engineering in Life Sciences, 11(2), 121-132. https://doi.org/10.1002/elsc.201000175

The development of microfluidic methodology that can be used in conjunction with drug screening and biomolecular diagnostics offers a route to evidence-based personalized medical care. Ideally, all personal diagnostics are best carried out in a rapid... Read More about Microsystems for personalized biomolecular diagnostics.

Cell sorting by endocytotic capacity in a microfluidic magnetophoresis device (2011)
Journal Article
Robert, D., Pamme, N., Conjeaud, H., Gazeau, F., Iles, A., & Wilhelm, C. (2011). Cell sorting by endocytotic capacity in a microfluidic magnetophoresis device. Lab on a chip, 11(11), 1902-1910. https://doi.org/10.1039/c0lc00656d

Magnetically labelled cells are finding a wealth of applications for in vitro analysis as well as in vivo treatments. Sorting of cells into subpopulations based on their magnetite loading is an important step in such procedures. Here, we study the so... Read More about Cell sorting by endocytotic capacity in a microfluidic magnetophoresis device.

Amine influence in vanadium-based ethylene polymerisation pro-catalysts bearing bis(phenolate) ligands with 'pendant' arms (2011)
Journal Article
Lorber, C., Despagnet-Ayoub, E., Vendier, L., Arbaoui, A., & Redshaw, C. (2011). Amine influence in vanadium-based ethylene polymerisation pro-catalysts bearing bis(phenolate) ligands with 'pendant' arms. Catalysis science & technology, 1(3), 489-494. https://doi.org/10.1039/c1cy00089f

Two families of vanadium complexes bearing diphenolate ligands with different 'pendant' arms have been screened under various conditions for the polymerisation behaviour of ethylene. The presence of a bound amine arm was found to favour enhanced ther... Read More about Amine influence in vanadium-based ethylene polymerisation pro-catalysts bearing bis(phenolate) ligands with 'pendant' arms.

Addressing fluorescence and liquid crystal behaviour in multi-mesogenic BODIPY materials (2011)
Journal Article
Benstead, M., Rosser, G. A., Beeby, A., Mehl, G. H., & Boyle, R. W. (2011). Addressing fluorescence and liquid crystal behaviour in multi-mesogenic BODIPY materials. New journal of chemistry = Nouveau journal de chimie, 35(7), 1410-1417. https://doi.org/10.1039/c0nj00990c

Two series of BODIPYs (4,4'-difluoro-3a, 4a-diaza-s-indacene) bearing mesogenic substituents have been synthesised and their fluorescent and self-assembly behaviour has been observed and characterised. In order to induce a strong preference for liqui... Read More about Addressing fluorescence and liquid crystal behaviour in multi-mesogenic BODIPY materials.

Flow focussing of particles and cells based on their intrinsic properties using a simple diamagnetic repulsion setup (2011)
Journal Article
Rodríguez-Villarreal, A. I., Tarn, M. D., Madden, L. A., Lutz, J. B., Greenman, J., Samitier, J., & Pamme, N. (2011). Flow focussing of particles and cells based on their intrinsic properties using a simple diamagnetic repulsion setup. Lab on a chip, 11(7), 1240-1248. https://doi.org/10.1039/c0lc00464b

The continuous flow focussing and manipulation of particles and cells are important factors in microfluidic applications for performing accurate and reproducible procedures downstream. Many particle focussing methods require complex setups or channel... Read More about Flow focussing of particles and cells based on their intrinsic properties using a simple diamagnetic repulsion setup.

Iron(II) and cobalt(II) complexes bearing 8-(1-aryliminoethylidene) quinaldines: Synthesis, characterization and ethylene dimerization behavior (2011)
Journal Article
Song, S., Xiao, T., Redshaw, C., Hao, X., Wang, F., & Sun, W. H. (2011). Iron(II) and cobalt(II) complexes bearing 8-(1-aryliminoethylidene) quinaldines: Synthesis, characterization and ethylene dimerization behavior. Journal of organometallic chemistry, 696(13), 2594-2599. https://doi.org/10.1016/j.jorganchem.2011.03.039

The series of bidentate N^N iron(II) and cobalt(II) complexes containing 8-(1-aryliminoethylidene) quinaldine derived ligands, 8-[2,6-(R 1)2-4-R2-C6H2NC (Me)]-2-Me-C10H5N, were synthesized and characterized by elemental and spectroscopic techniques.... Read More about Iron(II) and cobalt(II) complexes bearing 8-(1-aryliminoethylidene) quinaldines: Synthesis, characterization and ethylene dimerization behavior.

Compartmentalization and separation of aqueous reagents in the water droplets of water-in-oil high internal phase emulsions (2011)
Journal Article
Dunstan, T. S., & Fletcher, P. D. I. (2011). Compartmentalization and separation of aqueous reagents in the water droplets of water-in-oil high internal phase emulsions. Langmuir : the ACS journal of surfaces and colloids, 27(7), 3409-3415. https://doi.org/10.1021/la200058d

We have compartmentalised aqueous reagents and indicator species within the micron-sized water droplets of mixed high internal phase emulsions (HIPEs). Mass transport of the reagents across the micron-thickness oil films separating the water droplets... Read More about Compartmentalization and separation of aqueous reagents in the water droplets of water-in-oil high internal phase emulsions.

Identification of methicillin-resistant Staphylococcus aureus-specific peptides for targeted photoantimicrobial chemotherapy (2011)
Journal Article
Vince, R. V., Madden, L. A., Alonso, C. M., Savoie, H., Boyle, R. W., Todman, M., Paget, T., & Greenman, J. (2011). Identification of methicillin-resistant Staphylococcus aureus-specific peptides for targeted photoantimicrobial chemotherapy. Photochemical & photobiological sciences : an international journal, 10(4), 515-522. https://doi.org/10.1039/c0pp00267d

The increasing prevalence of multi-drug resistant bacteria, such as methicillin-resistant Staphylococcus aureus (MRSA), necessitates development of alternative modes of bacterial targeting which are not hindered by antibiotic resistance and minimise... Read More about Identification of methicillin-resistant Staphylococcus aureus-specific peptides for targeted photoantimicrobial chemotherapy.

Challenges in chelating positron emitting copper isotopes: tailored synthesis of unsymmetric chelators to form ultra stable complexes (2011)
Journal Article
Silversides, J. D., Smith, R., & Archibald, S. J. (2011). Challenges in chelating positron emitting copper isotopes: tailored synthesis of unsymmetric chelators to form ultra stable complexes. Dalton Transactions : an international journal of inorganic chemistry, 40(23), 6289-6297. https://doi.org/10.1039/c0dt01395a

The synthesis of chelators that form high stability complexes with copper(II) isotopes and do not suffer from transchelation in vivo has been a goal for many chemists. Such chelators will facilitate the exploitation of the Cu-64 isotope (t(1/2) = 12.... Read More about Challenges in chelating positron emitting copper isotopes: tailored synthesis of unsymmetric chelators to form ultra stable complexes.

Influence of the contact angle of silica nanoparticles at the air–water interface on the mechanical properties of the layers composed of these particles (2011)
Journal Article
Zang, D., Rio, E., Delon, G., Langevin, D., Wei, B., & Binks, B. (2011). Influence of the contact angle of silica nanoparticles at the air–water interface on the mechanical properties of the layers composed of these particles. Molecular Physics, 109(7-10), 1057-1066. https://doi.org/10.1080/00268976.2010.542778

We have studied the properties (surface pressure, compression and shear moduli, texture) of silica nanoparticle layers at the air-water interface. Particle hydrophobicity or, equivalently, the contact angle between particles, air and water, is the ma... Read More about Influence of the contact angle of silica nanoparticles at the air–water interface on the mechanical properties of the layers composed of these particles.

Two-dimensional colloidal alloys (2011)
Journal Article
Law, A. D., Buzza, D. M. A., & Horozov, T. S. (2011). Two-dimensional colloidal alloys. Physical review letters, 106(12), Article ARTN 128302. https://doi.org/10.1103/physrevlett.106.128302

We study the structure of mixed monolayers of large (3μm diameter) and small (1μm diameter) very hydrophobic silica particles at an octane-water interface as a function of the number fraction of small particles ξ. We find that a rich variety of two-d... Read More about Two-dimensional colloidal alloys.

2,6-dibenzhydryl- N -(2-phenyliminoacenaphthylenylidene)-4- methylbenzenamine nickel dibromides: Synthesis, characterization, and ethylene polymerization (2011)
Journal Article
Liu, H., Zhao, W., Hao, X., Redshaw, C., Huang, W., & Sun, W. H. (2011). 2,6-dibenzhydryl- N -(2-phenyliminoacenaphthylenylidene)-4- methylbenzenamine nickel dibromides: Synthesis, characterization, and ethylene polymerization. Organometallics, 30(8), 2418-2424. https://doi.org/10.1021/om200154a

A series of 2,6-dibenzhydryl-N-(2-phenyliminoacenaphthylenylidene)-4- methylbenzenamines (L1-L5) and the nickel(II) dibromide complexes thereof (C1-C5) were synthesized and fully characterized. The molecular structures of representative complexes wer... Read More about 2,6-dibenzhydryl- N -(2-phenyliminoacenaphthylenylidene)-4- methylbenzenamine nickel dibromides: Synthesis, characterization, and ethylene polymerization.

4,4′-Difluoro-4-bora-3a,4a-diaza-s-indacenes (BODIPYs) as components of novel light active materials (2011)
Journal Article
Benstead, M., Mehl, G. H., & Boyle, R. W. (2011). 4,4′-Difluoro-4-bora-3a,4a-diaza-s-indacenes (BODIPYs) as components of novel light active materials. Tetrahedron, 67(20), 3573-3601. https://doi.org/10.1016/j.tet.2011.03.028

Applications of BODIPY fluorophores as components of light active materials are reviewed.

Polyacrylamide nanoparticles as a delivery system in photodynamic therapy (2011)
Journal Article
Kuruppuarachchi, M., Lowry, A., Savoie, H., Alonso, C., & Boyle, R. W. (2011). Polyacrylamide nanoparticles as a delivery system in photodynamic therapy. Molecular pharmaceutics, 8(3), 920-931. https://doi.org/10.1021/mp200023y

Nanoparticles can be targeted towards, and accumulate in, tumor tissue by the enhanced permeability and retention effect, if sequestration by the reticuloendothelial system (RES) is avoided. The application of nanoparticles in the field of drug deliv... Read More about Polyacrylamide nanoparticles as a delivery system in photodynamic therapy.

Preparation, structural characterization, and thermal ammonolysis of two novel dimeric transition silylamide complexes (2011)
Journal Article
Cheng, F., Hope, C. N., Archibald, S. J., Bradley, J. S., Clark, S., Francesconi, M. G., Kelly, S. M., Young, N. A., & Lefebvre, F. (2011). Preparation, structural characterization, and thermal ammonolysis of two novel dimeric transition silylamide complexes. International Journal of Applied Ceramic Technology, 8(2), 467-481. https://doi.org/10.1111/j.1744-7402.2009.02452.x

The preparation and molecular structures of two novel dimeric transition metal silylamide complexes {Li0.5Zr[NHSi(NMe2)3]1.5[NSi(NMe2)3]0.5[μ -NSi(NMe2)3]}2 and {Li0.5Hf[NHSi(NMe2)3]1.5[NSi(NMe2)3]0.5[μ-NSi(NMe2)3]}2 with a tetrahedral coordination e... Read More about Preparation, structural characterization, and thermal ammonolysis of two novel dimeric transition silylamide complexes.

Synthesis and evaluation of a novel pyrenyl-appended triazole-based thiacalix[4]arene as a fluorescent sensor for Ag+ ion (2011)
Journal Article
Ni, X. L., Zeng, X., Redshaw, C., & Yamato, T. (2011). Synthesis and evaluation of a novel pyrenyl-appended triazole-based thiacalix[4]arene as a fluorescent sensor for Ag+ ion. Tetrahedron, 67(18), 3248-3253. https://doi.org/10.1016/j.tet.2011.03.008

New fluorescent chemosensors 1,3-alternate-1 and 2 with pyrenyl-appended triazole-based on thiacalix[4]arene were synthesized. The fluorescence spectra changes suggested that chemosensors 1 and 2 are highly selective for Ag + over other metal ions by... Read More about Synthesis and evaluation of a novel pyrenyl-appended triazole-based thiacalix[4]arene as a fluorescent sensor for Ag+ ion.

A chemically modified antibody mediates complete eradication of tumours by selective disruption of tumour blood vessels (2011)
Journal Article
Palumbo, A., Hauler, F., Dziunycz, P., Schwager, K., Soltermann, A., Pretto, F., Alonso, C., Hofbauer, G. F., Boyle, R. W., & Neri, D. (2011). A chemically modified antibody mediates complete eradication of tumours by selective disruption of tumour blood vessels. The British Journal of Cancer, 104(7), 1106-1115. https://doi.org/10.1038/bjc.2011.78

Background:The possibility of eradicating cancer by selective destruction of tumour blood vessels may represent an attractive therapeutic avenue, but most pharmaceutical agents investigated so far did not achieve complete cures and are not completely... Read More about A chemically modified antibody mediates complete eradication of tumours by selective disruption of tumour blood vessels.