All Outputs (1143)

Ir-catalysed N2O decomposition effect of Ir particle size and metal support interactions (2017)
Journal Article
Yentekakis, I., Goula, G., Kampouri, S., Betsi-argyropoulou, I., Panagiotopoulou, P., Taylor, M., Kyriakou, G., & Lambert, R. (2018). Ir-catalysed N2O decomposition effect of Ir particle size and metal support interactions. Catalysis Letters, 148(1), 341-347. https://doi.org/10.1007/s10562-017-2233-z

The effect of the morphology of Ir particles supported on γ-Al2O3, 8 mol%Y2O3-stabilized ZrO2 (YSZ), 10 mol%Gd2O3-doped CeO2 (GDC) and 80 wt%Al2O3–10 wt%CeO2–10 wt%ZrO2 (ACZ) on their stability on oxidative conditions, the associated metal–support in... Read More about Ir-catalysed N2O decomposition effect of Ir particle size and metal support interactions.

Coalescence of cluster beam generated sub-2 nm bare Au nanoparticles and analysis of Au film growth parameters (2017)
Journal Article
Verrelli, E., Michelakaki, I., Boukos, N., Kyriakou, G., & Tsoukalas, D. (2017). Coalescence of cluster beam generated sub-2 nm bare Au nanoparticles and analysis of Au film growth parameters. Annalen der Physik, 530(2), 1700256. https://doi.org/10.1002/andp.201700256

© 2017 by WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim In this work is presented the growth model for Au films grown on a carbon substrate at room temperature by using as building blocks Au nanoparticles (NPs) with 1.4 nm mean size generated via remo... Read More about Coalescence of cluster beam generated sub-2 nm bare Au nanoparticles and analysis of Au film growth parameters.

Ionic liquid droplet micro-reactor for catalysis reactions not at equilibrium (2017)
Journal Article
Zhang, M., Ettelaie, R., Yan, T., Zhang, S., Cheng, F., Binks, B. P., & Yang, H. (2017). Ionic liquid droplet micro-reactor for catalysis reactions not at equilibrium. Journal of the American Chemical Society, 139(48), 17387-17396. https://doi.org/10.1021/jacs.7b07731

We develop a novel strategy to more effectively and controllably process continuous enzymatic or homogeneous catalysis reactions based on non-aqueous Pickering emulsions. A key element of this strategy is “bottom-up” construction of a macroscale cont... Read More about Ionic liquid droplet micro-reactor for catalysis reactions not at equilibrium.

Correction: On-chip polyelectrolyte coating onto magnetic droplets – towards continuous flow assembly of drug delivery capsules (2017)
Journal Article
Alorabi, A. Q., Tarn, M. D., Gómez-Pastora, J., Bringas, E., Ortiz, I., Paunov, V. N., & Pamme, N. (2017). Correction: On-chip polyelectrolyte coating onto magnetic droplets – towards continuous flow assembly of drug delivery capsules. Lab on a chip, 17(22), 3934. https://doi.org/10.1039/c7lc90110k

Correction for ‘On-chip polyelectrolyte coating onto magnetic droplets – towards continuous flow assembly of drug delivery capsules’ by Ali Q. Alorabi et al., Lab Chip, 2017, DOI: 10.1039/c7lc00918f.

Superposition of translational and rotational motions under self-propulsion of liquid marbles filled by aqueous solutions of camphor (2017)
Journal Article
Bormashenko, E. Y., Frenkel, M., Bormashenko, Y., Chaniel, G., Valtsifer, V. A., & Binks, B. P. (2017). Superposition of translational and rotational motions under self-propulsion of liquid marbles filled by aqueous solutions of camphor. Langmuir : the ACS journal of surfaces and colloids, 33(46), 13234-13241. https://doi.org/10.1021/acs.langmuir.7b03356

Self-locomotion of liquid marbles, coated with lycopodium or fumed fluorosilica powder, filled with a saturated aqueous solution of camphor and placed on a water/vapor interface is reported. Self-propelled marbles demonstrated a complicated motion, r... Read More about Superposition of translational and rotational motions under self-propulsion of liquid marbles filled by aqueous solutions of camphor.

High throughput fabrication of cell spheroids by templating water-in-water Pickering emulsions (2017)
Journal Article
Das, A. A. K., Filby, B. W., Geddes, D. A., Legrande, D., & Paunov, V. N. (2017). High throughput fabrication of cell spheroids by templating water-in-water Pickering emulsions. Materials Horizons, 4(6), 1196-1200. https://doi.org/10.1039/c7mh00677b

© The Royal Society of Chemistry 2017. We report a simple technique for the high throughput generation of tissue spheroids based on the encapsulation of dispersed adherent cells in particle-stabilised water-in-water emulsions. We demonstrate cell enc... Read More about High throughput fabrication of cell spheroids by templating water-in-water Pickering emulsions.

Sound transmission loss of hierarchically porous composites produced by hydrogel templating and viscous trapping techniques (2017)
Journal Article
Thompson, B. R., Taylor, B. L., Qin, Q., Stoyanov, S. D., Horozov, T. S., & Paunov, V. N. (2017). Sound transmission loss of hierarchically porous composites produced by hydrogel templating and viscous trapping techniques. Materials Chemistry Frontiers, 1(12), 2627-2637. https://doi.org/10.1039/c7qm00371d

© 2017 the Partner Organisations. We have developed two different methods for fabrication of hierarchically porous composites which are environmentally friendly, inexpensive and give a large amount of control over the composite microstructure. The hy... Read More about Sound transmission loss of hierarchically porous composites produced by hydrogel templating and viscous trapping techniques.

One-pot synthesis of {Mo6I8}4+-doped polystyrene microspheres via a free radical dispersion copolymerisation reaction (2017)
Journal Article
Vorotnikova, N. A., Edeleva, M. V., Kurskaya, O. G., Brylev, K. A., Shestopalov, A. M., Mironov, Y. V., Sutherland, A. J., Efremova, O. A., & Shestopalov, M. A. (2017). One-pot synthesis of {Mo6I8}4+-doped polystyrene microspheres via a free radical dispersion copolymerisation reaction. Polymer international, 66(12), 1906-1912. https://doi.org/10.1002/pi.5473

© 2017 Society of Chemical Industry Molybdenum octahedral clusters, when incorporated into an appropriate polymer matrix, are considered as promising agents for a range of biological applications. This work describes the one-pot synthesis, morphology... Read More about One-pot synthesis of {Mo6I8}4+-doped polystyrene microspheres via a free radical dispersion copolymerisation reaction.

Hierarchically porous composites fabricated by hydrogel templating and viscous trapping techniques (2017)
Journal Article
Thompson, B. R., Horozov, T. S., Stoyanov, S. D., & Paunov, V. N. (2018). Hierarchically porous composites fabricated by hydrogel templating and viscous trapping techniques. Materials & design, 137, 384-393. https://doi.org/10.1016/j.matdes.2017.10.046

© 2017 Elsevier Ltd Two methods for the preparation of hierarchically porous composites have been developed and explored. The first involved templating mixed slurries of hydrogel beads with two different average bead size distributions with gypsum sl... Read More about Hierarchically porous composites fabricated by hydrogel templating and viscous trapping techniques.

Fabrication of tailorable pH responsive cationic amphiphilic microgels on a microfluidic device for drug release (2017)
Journal Article
Lu, B., Tarn, M. D., Pamme, N., & Georgiou, T. K. (2018). Fabrication of tailorable pH responsive cationic amphiphilic microgels on a microfluidic device for drug release. Journal of Polymer Science Part A: Polymer Chemistry, 56(1), 59-66. https://doi.org/10.1002/pola.28860

Cationic, amphiphilic microgels of differing compositions based on hydrophilic, pH, and thermoresponsive 2-(dimethylamino)ethyl methacrylate (DMAEMA) and hydrophobic, nonionic n-butyl acrylate (BuA) are synthesized using a lab-on-a-chip device. Hydro... Read More about Fabrication of tailorable pH responsive cationic amphiphilic microgels on a microfluidic device for drug release.

Magnetic control of MOF crystal orientation and alignment (2017)
Journal Article
Cheng, F., Marshall, E. S., Young, A. J., Robinson, P. J., Bouillard, J. S. G., Adawi, A. M., Vermeulen, N. A., Farha, O. K., Reithofer, M. R., & Chin, J. M. (2017). Magnetic control of MOF crystal orientation and alignment. Chemistry: a European journal, 23(62), 15578-15582. https://doi.org/10.1002/chem.201703812

Most metal-organic frameworks (MOFs) possess anisotropic properties, the full exploitation of which necessitates a general strategy for the controllable orientation of such MOF crystals. Current methods largely rely upon layer-by-layer MOF epitaxy or... Read More about Magnetic control of MOF crystal orientation and alignment.

On-chip polyelectrolyte coating onto magnetic droplets – towards continuous flow assembly of drug delivery capsules (2017)
Journal Article
Alorabi, A. Q., Tarn, M. D., Gómez-Pastora, J., Bringas, E., Ortiz, I., Paunov, V. N., & Pamme, N. (2017). On-chip polyelectrolyte coating onto magnetic droplets – towards continuous flow assembly of drug delivery capsules. Lab on a chip, 17(22), 3785-3795. https://doi.org/10.1039/c7lc00918f

Polyelectrolyte (PE) microcapsules for drug delivery are typically fabricated via layer-by-layer (LbL) deposition of PE layers of alternating charge on sacrificial template microparticles, which usually requires multiple incubation and washing steps... Read More about On-chip polyelectrolyte coating onto magnetic droplets – towards continuous flow assembly of drug delivery capsules.

Converting metal-organic framework particles from hydrophilic to hydrophobic by an interfacial assembling route (2017)
Journal Article
Zhang, F., Sang, X., Tan, X., Liu, C., Zhang, J., Luo, T., Liu, L., Han, B., Yang, G., & Binks, B. P. (2017). Converting metal-organic framework particles from hydrophilic to hydrophobic by an interfacial assembling route. Langmuir : the ACS journal of surfaces and colloids, 33(43), 12427-12433. https://doi.org/10.1021/acs.langmuir.7b02365

Here we propose to modify the hydrophilicity of metal-organic framework (MOF) particles by an interfacial assembling route, which is based on the surface-active nature of MOF particles. It was found that hydrophilic UiO-66-NH₂ particles can be conver... Read More about Converting metal-organic framework particles from hydrophilic to hydrophobic by an interfacial assembling route.

Highly selective recognition of Al3+ and I- ions using a bifunctional fluorescent probe (2017)
Journal Article
Li, Z., Zhao, J.-L., Wu, Y.-T., Mu, L., Zeng, X., Jin, Z., Wei, G., Xie, N., & Redshaw, C. (2017). Highly selective recognition of Al3+ and I- ions using a bifunctional fluorescent probe. Organic & biomolecular chemistry, 15(40), 8627-8633. https://doi.org/10.1039/C7OB02301D

A tripodal fluorescent probe L1 armed with rhodamine B and 1-naphthaleneisothiocyanates was prepared in high yield. A study of the recognition properties revealed that probe L1 exhibited high sensitivity and selectivity towards Al3⁺ through a “FRET”... Read More about Highly selective recognition of Al3+ and I- ions using a bifunctional fluorescent probe.

Enhanced antimicrobial effect of berberine in nanogel carriers with cationic surface functionality (2017)
Journal Article
Al-Awady, M. J., Fauchet, A., Greenway, G. M., & Paunov, V. N. (2017). Enhanced antimicrobial effect of berberine in nanogel carriers with cationic surface functionality. Journal of Materials Chemistry B, 5(38), 7885-7897. https://doi.org/10.1039/c7tb02262j

We report a strong enhancement in the antimicrobial action of berberine encapsulated into polyacrylic acid-based nanogels followed by further surface functionalisation with a cationic polyelectrolyte (PDAC). Due to the highly developed surface area,... Read More about Enhanced antimicrobial effect of berberine in nanogel carriers with cationic surface functionality.

Dual wavelength (ultraviolet and green) photodetectors using solution processed zinc oxide nanoparticles (2017)
Journal Article
O'Neill, M., Ibrahem, M. A., Verrelli, E., Lai, K. T., Kyriakou, G., Lee, A. F., Isaacs, M. A., Cheng, F., & O’Neill, M. (2017). Dual wavelength (ultraviolet and green) photodetectors using solution processed zinc oxide nanoparticles. ACS Applied Materials & Interfaces, 9(42), 36971-36979. https://doi.org/10.1021/acsami.7b08092

Narrow-band photoconductivity with a spectral width of 0.16 eV is obtained from solution-processed colloidal ZnO nanocrystals beneath the band-edge at 2.25 eV. A new model involving electron transfer from deep defects to discrete shallow donors is in... Read More about Dual wavelength (ultraviolet and green) photodetectors using solution processed zinc oxide nanoparticles.

Modeling the interfacial energy of surfactant-free amphiphilic Janus nanoparticles from phase inversion in Pickering emulsions (2017)
Journal Article
Wu, D., Binks, B. P., & Honciuc, A. (2018). Modeling the interfacial energy of surfactant-free amphiphilic Janus nanoparticles from phase inversion in Pickering emulsions. Langmuir : the ACS journal of surfaces and colloids, 34(3), 1225-1233. https://doi.org/10.1021/acs.langmuir.7b02331

Determining the interfacial energy of nanoparticles is very challenging via traditional methods that first require measuring the contact angle of several liquids of a sessile drop on pellets or capillary rise in powder beds. In this work, we propose... Read More about Modeling the interfacial energy of surfactant-free amphiphilic Janus nanoparticles from phase inversion in Pickering emulsions.

An ultra melt-resistant hydrogel from food grade carbohydrates (2017)
Journal Article
Thompson, B. R., Horozov, T. S., Stoyanov, S. D., & Paunov, V. N. (2017). An ultra melt-resistant hydrogel from food grade carbohydrates. RSC advances, 7(72), 45535-45544. https://doi.org/10.1039/c7ra08590g

© 2017 The Royal Society of Chemistry. We report a binary hydrogel system made from two food grade biopolymers, agar and methylcellulose (agar-MC), which does not require addition of salt for gelation to occur and has very unusual rheological and the... Read More about An ultra melt-resistant hydrogel from food grade carbohydrates.

Silicon diimide gel as an efficient stationary phase in thin layer chromatography for acid-sensitive organic compounds (2017)
Journal Article
Kitney, S. P., Sajedin, S. M., Rocher, V., Cheng, F., & Kelly, S. M. (2017). Silicon diimide gel as an efficient stationary phase in thin layer chromatography for acid-sensitive organic compounds. Chemical communications : Chem comm / the Royal Society of Chemistry, 53(80), 11080-11082. https://doi.org/10.1039/c7cc04952h

We report the use of mesoporous silicon diimide gel as a basic stationary phase in thin layer chromatography for the characterisation and purification of acid-sensitive compounds. The gel is prepared by a simple sol-gel process and exhibits a large s... Read More about Silicon diimide gel as an efficient stationary phase in thin layer chromatography for acid-sensitive organic compounds.

Nanoparticulate Pd-Sn Compounds Supported on Metal Oxides: Synthesis, Material and Catalytic Properties (2017)
Journal Article
Ibhadon, A. O., Francesconi, M. G., & Johnston, S. K. (2017). Nanoparticulate Pd-Sn Compounds Supported on Metal Oxides: Synthesis, Material and Catalytic Properties. Chemical Engineering & Process Techniques, 3(3), Article 1044

The manufacture of chemicals requires innovation at the catalyst frontier so that processes can be developed with higher energy efficiency and increased facility of separation and recovery of products. Catalysts with high selectivity and activity con... Read More about Nanoparticulate Pd-Sn Compounds Supported on Metal Oxides: Synthesis, Material and Catalytic Properties.