Shijie Yu
Biphasic biocatalysis using a CO2-switchable Pickering emulsion
Yu, Shijie; Zhang, Duyan; Jiang, Jianzhong; Cui, Zhenggang; Xia, Wenshui; Binks, Bernard P.; Yang, Hengquan
Authors
Duyan Zhang
Jianzhong Jiang
Zhenggang Cui
Wenshui Xia
Bernard P. Binks
Hengquan Yang
Abstract
Biphasic biocatalyses such as the hydrolysis of olive oil and the esterification of octanol with oleic acid were performed in a CO2/N2-switchable Pickering oil-in-water emulsion stabilized by silica nanoparticles hydrophobized in situ by a CO2/N2-switchable surfactant (N,N-dimethyldodecylamine). Compared with biphasic systems, the enzyme in the Pickering emulsions displays a higher reaction efficiency, and demulsification and recycling of the enzyme can be simply realized by bubbling with N2/CO2. Moreover, the recycled enzyme still possesses significant catalytic activity.
Citation
Yu, S., Zhang, D., Jiang, J., Cui, Z., Xia, W., Binks, B. P., & Yang, H. (2019). Biphasic biocatalysis using a CO2-switchable Pickering emulsion. Green chemistry : an international journal and green chemistry resource : GC, 21(15), 4062-4068. https://doi.org/10.1039/c8gc03879a
Journal Article Type | Article |
---|---|
Acceptance Date | May 10, 2019 |
Online Publication Date | May 10, 2019 |
Publication Date | May 10, 2019 |
Deposit Date | May 23, 2019 |
Publicly Available Date | May 11, 2020 |
Journal | Green Chemistry |
Print ISSN | 1463-9262 |
Electronic ISSN | 1463-9270 |
Publisher | Royal Society of Chemistry |
Peer Reviewed | Peer Reviewed |
Volume | 21 |
Issue | 15 |
Pages | 4062-4068 |
DOI | https://doi.org/10.1039/c8gc03879a |
Keywords | Pollution; Environmental Chemistry |
Public URL | https://hull-repository.worktribe.com/output/1834929 |
Publisher URL | https://pubs.rsc.org/en/content/articlelanding/2019/gc/c8gc03879a#!divAbstract |
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©2019 The authors
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