Photoluminescent materials based on PMMA and a highly-emissive octahedral molybdenum metal cluster complex

Vejsadova, Lucie; Efremova, Olga A.; Brylev, Konstantin A.; Chimonides, Gwen F.; Kim, Sung-Jin; Kitamura, Noboru; Mikes, Petr; Shestopalov, Michael A.; Sutherland, Andrew J.; Topham, Paul D.; Vejsadová, Lucie; Vorotnikov, Yuri A.

Abstract

Materials that combine photoluminescence, optical transparency and facile processability are of high importance in many applications. This article reports on the development of photoluminescent poly(methyl methacrylate) materials based on novel highly emissive anionic molybdenum cluster complex [{Mo₆I₈}(OTs)₆]²⁻ (where OTs⁻ is the p-toluenesulfonate ion). The materials were obtained by both solution and bulk copolymerisation of methyl methacrylate and (dMDAEMA)₂ [{Mo₆I₈}(OTs)₆], where dMDAEMA⁺ is the polymerisable cation [2-(methacryloyloxy)ethyl]dimethyl-dodecylammonium. Evaluation of the resultant hybrid materials showed that one could combine the excellent photoluminescent properties of the cluster complex with the transparency and processability of PMMA.

Citation

Vejsadova, L., Efremova, O. A., Brylev, K. A., Chimonides, G. F., Kim, S.-J., Kitamura, N., Mikes, P., Shestopalov, M. A., Sutherland, A. J., Topham, P. D., Vejsadová, L., & Vorotnikov, Y. A. (2016). Photoluminescent materials based on PMMA and a highly-emissive octahedral molybdenum metal cluster complex. Journal of Materials Chemistry C, 4(3), 497-503. https://doi.org/10.1039/c5tc03204k

• Acceptance Date: Dec 11, 2015
• Online Publication Date: Dec 14, 2015
• Publication Date: Jan 1, 2016
• Deposit Date: Dec 23, 2015
• Publicly Available Date: Nov 23, 2017
• Journal: Journal of materials chemistry C
• Print ISSN: 2050-7526
• Electronic ISSN: 2050-7534
• Publisher: Royal Society of Chemistry
• Peer Reviewed: Peer Reviewed
• Volume: 4
• Issue: 3
• Pages: 497-503
• DOI: https://doi.org/10.1039/c5tc03204k
• Keywords: Materials Chemistry; General Chemistry
• Public URL: https://hull-repository.worktribe.com/output/383451
• Publisher URL: http://pubs.rsc.org/en/Content/ArticleLanding/2016/TC/C5TC03204K#!divAbstract
• Additional Information: This is a description of an article published in: Journal of materials chemistry C, 2015, v.4 issue 3.
• Contract Date: Nov 23, 2017