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Photoluminescent materials based on PMMA and a highly-emissive octahedral molybdenum metal cluster complex

Vejsadova, Lucie; Efremova, Olga A.; Brylev, Konstantin A.; Chimonides, Gwen F.; Kim, Sung-Jin; Kitamura, Noboru; Mikes, Petr; Shestopalov, Michael A.; Sutherland, Andrew J.; Topham, Paul D.; Vejsadová, Lucie; Vorotnikov, Yuri A.

Authors

Lucie Vejsadova

Olga A. Efremova

Konstantin A. Brylev

Gwen F. Chimonides

Sung-Jin Kim

Noboru Kitamura

Petr Mikes

Michael A. Shestopalov

Andrew J. Sutherland

Paul D. Topham

Lucie Vejsadová

Yuri A. Vorotnikov



Abstract

Materials that combine photoluminescence, optical transparency and facile processability are of high importance in many applications. This article reports on the development of photoluminescent poly(methyl methacrylate) materials based on novel highly emissive anionic molybdenum cluster complex [{Mo₆I₈}(OTs)₆]²⁻ (where OTs⁻ is the p-toluenesulfonate ion). The materials were obtained by both solution and bulk copolymerisation of methyl methacrylate and (dMDAEMA)₂ [{Mo₆I₈}(OTs)₆], where dMDAEMA⁺ is the polymerisable cation [2-(methacryloyloxy)ethyl]dimethyl-dodecylammonium. Evaluation of the resultant hybrid materials showed that one could combine the excellent photoluminescent properties of the cluster complex with the transparency and processability of PMMA.

Citation

Vejsadova, L., Efremova, O. A., Brylev, K. A., Chimonides, G. F., Kim, S., Kitamura, N., …Vorotnikov, Y. A. (2016). Photoluminescent materials based on PMMA and a highly-emissive octahedral molybdenum metal cluster complex. Journal of materials chemistry. C, 4(3), 497-503. https://doi.org/10.1039/c5tc03204k

Acceptance Date Dec 11, 2015
Online Publication Date Dec 14, 2015
Publication Date Jan 1, 2016
Deposit Date Dec 23, 2015
Publicly Available Date Nov 23, 2017
Journal Journal of Materials Chemistry C
Print ISSN 2050-7526
Electronic ISSN 2050-7526
Publisher Royal Society of Chemistry
Peer Reviewed Peer Reviewed
Volume 4
Issue 3
Pages 497-503
DOI https://doi.org/10.1039/c5tc03204k
Keywords Materials Chemistry; General Chemistry
Public URL https://hull-repository.worktribe.com/output/383451
Publisher URL http://pubs.rsc.org/en/Content/ArticleLanding/2016/TC/C5TC03204K#!divAbstract
Copyright Statement This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Additional Information This is a description of an article published in: Journal of materials chemistry C, 2015, v.4 issue 3.

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