New dual-mode orthogonal tunable fluorescence systems based on cucurbit[8]uril: White light, 3D printing, and anti-counterfeit applications

Zhang, Ting Ting; Yang, Xi Nan; Hu, Jian Hang; Luo, Yang; Liu, Hou Jing; Tao, Zhu; Xiao, Xin; Redshaw, Carl

Abstract

In this work, we have utilized a supramolecular approach to control emission, and generate white light and have applied the system to both 3D printing and counterfeiting applications. In particular, we report two new dual-mode orthogonal tunable fluorescence systems, A and B. System A is based on the fluorescent dyes perylene diimide (PDI-C6) and 7-hydroxycoumarin, which are incorporated into the main guest system, namely cucurbit[8]uril (Q[8]). This system can provide bright white emission and proved to be adaptable, whereby the emission can be easily changed via temperature control; a smart temperature control switch in the range of 30 °C to 100 °C was developed. System B is based on quinine sulfate with PDI-C6 and Q[8], and this system can provide white emission over a wide concentration range and it was applied to LED lamps. Such white emission also performs well in polymeric matrices and can be utilized for 3D printing, whilst solutions can be used for more practical applications, for example as anti-counterfeiting materials.

Citation

Zhang, T. T., Yang, X. N., Hu, J. H., Luo, Y., Liu, H. J., Tao, Z., …Redshaw, C. (2023). New dual-mode orthogonal tunable fluorescence systems based on cucurbit[8]uril: White light, 3D printing, and anti-counterfeit applications. Chemical Engineering Journal, 452, Article 138960. https://doi.org/10.1016/j.cej.2022.138960

• Journal Article Type: Article
• Acceptance Date: Aug 29, 2022
• Online Publication Date: Sep 14, 2022
• Publication Date: Jan 15, 2023
• Deposit Date: Sep 14, 2022
• Publicly Available Date: Sep 15, 2022
• Journal: Chemical Engineering Journal
• Print ISSN: 1385-8947
• Publisher: Elsevier
• Peer Reviewed: Peer Reviewed
• Volume: 452
• Article Number: 138960
• DOI: https://doi.org/10.1016/j.cej.2022.138960
• Keywords: Supramolecular approach; Perylene; White light emission; Host-guest interaction; Cucurbit[n]urils
• Public URL: https://hull-repository.worktribe.com/output/4076352