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Water-soluble hybrid materials based on {Mo₆X₈}⁴⁺ (X = Cl, Br, I) cluster complexes and sodium polystyrene sulfonate

Solovieva, Anastasiya O.; Vorotnikov, Yuri A.; Svezhentseva, Ekaterina V.; Kurskaya, Olga G.; Brylev, Konstantin A.; Tsygankova, Alphiya R.; Edeleva, Mariya V.; Gyrylova, Svetlana N.; Shestopalov, Michael A.; Mironov, Yuri V.; Shestopalov, Alexander M.; Efremova, Olga A.; Brylev, Konstantin; Edeleva, Mariya; Gyrylova, Svetlana; Kitamura, Noboru; Kurskaya, Olga; Mironov, Yuri; Shestopalov, Alexander; Shestopalov, Michael; Solovieva, Anastasiya; Svezhentseva, Ekaterina; Tsygankova, Alphiya; Vorotnikov, Yuri

Authors

Anastasiya O. Solovieva

Yuri A. Vorotnikov

Ekaterina V. Svezhentseva

Olga G. Kurskaya

Konstantin A. Brylev

Alphiya R. Tsygankova

Mariya V. Edeleva

Svetlana N. Gyrylova

Michael A. Shestopalov

Yuri V. Mironov

Alexander M. Shestopalov

Olga A. Efremova

Konstantin Brylev

Mariya Edeleva

Svetlana Gyrylova

Noboru Kitamura

Olga Kurskaya

Yuri Mironov

Alexander Shestopalov

Michael Shestopalov

Anastasiya Solovieva

Ekaterina Svezhentseva

Alphiya Tsygankova

Yuri Vorotnikov



Abstract

Development of water-soluble forms of octahedral molybdenum clusters {Mo₆X₈}⁴⁺ (X = Cl, Br, I) is strongly motivated by the tremendous potential that these complexes have for biological applications, namely as agents for bioimaging and photodynamic therapy. In these work we report the first water-soluble hybrid materials, which represent sodium polystyrene sulfonate doped by molybdenum clusters, and evaluation of their photophysical and biological properties (dark and photoinduced cytotoxicity and cellular uptake) with the use of cervical cancer (HeLa) and human epidermoid larynx carcinoma (Hep-2) cell-lines as models.

Citation

Solovieva, A. O., Vorotnikov, Y. A., Svezhentseva, E. V., Kurskaya, O. G., Brylev, K. A., Tsygankova, A. R., …Vorotnikov, Y. (2017). Water-soluble hybrid materials based on {Mo₆X₈}⁴⁺ (X = Cl, Br, I) cluster complexes and sodium polystyrene sulfonate. New journal of chemistry = Nouveau journal de chimie, 41(4), 1670-1676. https://doi.org/10.1039/c6nj03469a

Journal Article Type Article
Acceptance Date Jan 4, 2017
Publication Date Jan 5, 2017
Deposit Date Jan 6, 2017
Publicly Available Date Mar 29, 2024
Journal New journal of chemistry
Print ISSN 1144-0546
Electronic ISSN 1369-9261
Publisher Royal Society of Chemistry
Peer Reviewed Peer Reviewed
Volume 41
Issue 4
Pages 1670-1676
DOI https://doi.org/10.1039/c6nj03469a
Keywords Materials Chemistry; General Chemistry; Catalysis
Public URL https://hull-repository.worktribe.com/output/472192
Publisher URL http://pubs.rsc.org/en/Content/ArticleLanding/2017/NJ/C6NJ03469A#!divCitation
Additional Information : This document is Similarity Check deposited; : Supplementary Information; : Yuri A. Vorotnikov (ORCID); : Yuri A. Vorotnikov (ResearcherID); : Alphiya R. Tsygankova (ResearcherID); : Olga A. Efremova (ORCID); : Michael A. Shestopalov (ORCID); : Michael A. Shestopalov (ResearcherID); : The Royal Society of Chemistry and the partner society(ies) have an exclusive publication licence for this journal; OPEN ACCESS: This article is freely available. This article is licensed under a Creative Commons Attribution Non Commercial 3.0 Unported Licence (CC BY-NC 3.0); : Single-blind; : Received 4 November 2016; Accepted 4 January 2017; Accepted Manuscript published 5 January 2017; Advance Article published 24 January 2017; Version of Record published 13 February 2017

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