Water-soluble hybrid materials based on {Mo₆X₈}⁴⁺ (X = Cl, Br, I) cluster complexes and sodium polystyrene sulfonate

Solovieva, Anastasiya O.; Vorotnikov, Yuri A.; Svezhentseva, Ekaterina V.; Kurskaya, Olga G.; Brylev, Konstantin A.; Tsygankova, Alphiya R.; Edeleva, Mariya V.; Gyrylova, Svetlana N.; Shestopalov, Michael A.; Mironov, Yuri V.; Shestopalov, Alexander M.; Efremova, Olga A.; Brylev, Konstantin; Edeleva, Mariya; Gyrylova, Svetlana; Kitamura, Noboru; Kurskaya, Olga; Mironov, Yuri; Shestopalov, Alexander; Shestopalov, Michael; Solovieva, Anastasiya; Svezhentseva, Ekaterina; Tsygankova, Alphiya; Vorotnikov, Yuri

Abstract

Development of water-soluble forms of octahedral molybdenum clusters {Mo₆X₈}⁴⁺ (X = Cl, Br, I) is strongly motivated by the tremendous potential that these complexes have for biological applications, namely as agents for bioimaging and photodynamic therapy. In these work we report the first water-soluble hybrid materials, which represent sodium polystyrene sulfonate doped by molybdenum clusters, and evaluation of their photophysical and biological properties (dark and photoinduced cytotoxicity and cellular uptake) with the use of cervical cancer (HeLa) and human epidermoid larynx carcinoma (Hep-2) cell-lines as models.

Citation

Solovieva, A. O., Vorotnikov, Y. A., Svezhentseva, E. V., Kurskaya, O. G., Brylev, K. A., Tsygankova, A. R., Edeleva, M. V., Gyrylova, S. N., Shestopalov, M. A., Mironov, Y. V., Shestopalov, A. M., Efremova, O. A., Brylev, K., Edeleva, M., Gyrylova, S., Kitamura, N., Kurskaya, O., Mironov, Y., Shestopalov, A., Shestopalov, M., …Vorotnikov, Y. (2017). Water-soluble hybrid materials based on {Mo₆X₈}⁴⁺ (X = Cl, Br, I) cluster complexes and sodium polystyrene sulfonate. New journal of chemistry = Nouveau journal de chimie, 41(4), 1670-1676. https://doi.org/10.1039/c6nj03469a

• Journal Article Type: Article
• Acceptance Date: Jan 4, 2017
• Publication Date: Jan 5, 2017
• Deposit Date: Jan 6, 2017
• Publicly Available Date: Jan 10, 2018
• Journal: New journal of chemistry
• Print ISSN: 1144-0546
• Publisher: Royal Society of Chemistry
• Peer Reviewed: Peer Reviewed
• Volume: 41
• Issue: 4
• Pages: 1670-1676
• DOI: https://doi.org/10.1039/c6nj03469a
• Keywords: Materials Chemistry; General Chemistry; Catalysis
• Public URL: https://hull-repository.worktribe.com/output/472192
• Publisher URL: http://pubs.rsc.org/en/Content/ArticleLanding/2017/NJ/C6NJ03469A#!divCitation
• Additional Information: : This document is Similarity Check deposited; : Supplementary Information; : Yuri A. Vorotnikov (ORCID); : Yuri A. Vorotnikov (ResearcherID); : Alphiya R. Tsygankova (ResearcherID); : Olga A. Efremova (ORCID); : Michael A. Shestopalov (ORCID); : Michael A. Shestopalov (ResearcherID); : The Royal Society of Chemistry and the partner society(ies) have an exclusive publication licence for this journal; OPEN ACCESS: This article is freely available. This article is licensed under a Creative Commons Attribution Non Commercial 3.0 Unported Licence (CC BY-NC 3.0); : Single-blind; : Received 4 November 2016; Accepted 4 January 2017; Accepted Manuscript published 5 January 2017; Advance Article published 24 January 2017; Version of Record published 13 February 2017
• Contract Date: Jan 10, 2018