A versatile family of interconvertible microporous chiral molecular frameworks: The first example of ligand control of network chirality

Kepert, C. J.; Prior, T. J.; Rosseinsky, M. J.

doi:10.1021/ja993814s

Putting pressure on elusive polymorphs and solvates (2008)
Journal Article
Oswald, I. D. H., Chataigner, I., Elphick, S., Fabbiani, F. P. A., Lennie, A. R., Maddaluno, J., Marshall, W. G., Prior, T. J., Pulham, C. R., & Smith, R. I. (2009). Putting pressure on elusive polymorphs and solvates. CrystEngComm RSC, 11(2), 359-366. https://doi.org/10.1039/b814471k

The reproducible crystallisation of elusive polymorphs and solvates of molecular compounds at high pressure has been demonstrated through studies on maleic acid, malonamide, and paracetamol. These high-pressure methods can be scaled-up to produce 'bu... Read More about Putting pressure on elusive polymorphs and solvates.

Reactivity of the N-heterocyclic carbene complexes [Ru(IMes)(2)(CO)HX] (X = OH, Cl) with alkynes (2008)
Journal Article
Chatwin, S. L., Mahon, M. F., Prior, T. J., & Whittlesey, M. K. (2010). Reactivity of the N-heterocyclic carbene complexes [Ru(IMes)(2)(CO)HX] (X = OH, Cl) with alkynes. Inorganica Chimica Acta, 363(3), 625-632. https://doi.org/10.1016/j.ica.2008.11.013

Treatment of the 16-electron hydroxy hydride complex [Ru(IMes)(2)(CO)H(OH)] (1, IMes = 1,3-bis-(2,4,6-trimethylphenyl)imidazol-2-ylidene) with HC CR affords the alkynyl species [Ru(IMes)(2)(CO) H(C CR)] (R = Ph 3, SiMe3, 4) and [Ru(IMes)(2)(CO)(C... Read More about Reactivity of the N-heterocyclic carbene complexes [Ru(IMes)(2)(CO)HX] (X = OH, Cl) with alkynes.

The dimeric "hand-shake" motif in complexes and metallo-supramolecular assemblies of cyclotriveratrylene-based ligands (2008)
Journal Article
Carruthers, C., Ronson, T. K., Sumby, C. J., Westcott, A., Harding, L. P., Prior, T. J., Rizkallah, P., & Hardie, M. J. (2008). The dimeric "hand-shake" motif in complexes and metallo-supramolecular assemblies of cyclotriveratrylene-based ligands. Chemistry: a European journal, 14(33), 10286-10296. https://doi.org/10.1002/chem.200801264

A series of clathrate and metal complexes with cyclotriveratrylene-like molecular host ligands show a similar dimeric homomeric inclusion motif in which a ligand arm of one host is the intra-cavity guest of another and vice versa. This "hand-shake" m... Read More about The dimeric "hand-shake" motif in complexes and metallo-supramolecular assemblies of cyclotriveratrylene-based ligands.

Cobalt(ethylenediamine)sulfate: A pillared layered coordination polymer (2008)
Journal Article
Lauchan, S., Prior, T. J., Meansiri, S., & Rujiwatra, A. (2008). Cobalt(ethylenediamine)sulfate: A pillared layered coordination polymer. Journal of inorganic and organometallic polymers and materials, 18(3), 352-357. https://doi.org/10.1007/s10904-008-9208-x

A pillared-layered coordination polymer of formula Co(H2NCH2CH2NH2)SO4 (1) has been synthesized under solvothermal condition, and fully characterized. The three-dimensional structure of 1 is built up from cobalt sulfate sheets, each of which is compo... Read More about Cobalt(ethylenediamine)sulfate: A pillared layered coordination polymer.

Synthesis and characterization of two metallic spin-glass phases of Fe Mo4 Ge3 (2008)
Journal Article
Baker, P. J., Battle, P. D., Blundell, S. J., Grandjean, F., Lancaster, T., Long, G. J., Oldham, S. E., & Prior, T. J. (2008). Synthesis and characterization of two metallic spin-glass phases of Fe Mo4 Ge3. Physical review B: Condensed matter and materials physics, 77(13), 134405-1 - 134405-13. https://doi.org/10.1103/physrevb.77.134405

Polycrystalline samples of Fe Mo4 Ge3 have been synthesized by the reduction of an oxide mixture at 1248 K and characterized by a combination of diffraction, muon spin relaxation (μ+ SR), Mössbauer spectroscopy, magnetometry, transport, and heat-capa... Read More about Synthesis and characterization of two metallic spin-glass phases of Fe Mo4 Ge3.

New network structures from Cu(II) complexes of chelating ligands with appended hydrogen bonding sites (2008)
Journal Article
Stephenson, M. D., Prior, T. J., & Hardie, M. J. (2008). New network structures from Cu(II) complexes of chelating ligands with appended hydrogen bonding sites. Crystal growth & design, 8(2), 643-653. https://doi.org/10.1021/cg700820d

Complexes [Cu(phenpyzda)Cl-2(H2O)]center dot H2O (1) and [Cu(phenpyzda)Br-2(H2O)]center dot 2H(2)O (2), where phenpyzda = pyrazino[2,3-f][1,10]phenanthroline-2,3-diamide, show similar molecular structures with square planar Cu(II). Each complex has a... Read More about New network structures from Cu(II) complexes of chelating ligands with appended hydrogen bonding sites.

Concomitant hydrate polymorphism in the precipitation of sparfloxacin from aqueous solution (2008)
Journal Article
Llinàs, A., Burley, J. C., Prior, T. J., Glen, R. C., & Goodman, J. M. (2008). Concomitant hydrate polymorphism in the precipitation of sparfloxacin from aqueous solution. Crystal growth & design, 8(1), 114-118. https://doi.org/10.1021/cg700908m

The Potentiometric Cycling for Polymorph Creation [PC](2) has been applied to sparfloxacin, a third-generation fluoroquinolone antibiotic. Two different trihydrate phases precipitate from aqueous solution. X-ray data indicate that one of these is a p... Read More about Concomitant hydrate polymorphism in the precipitation of sparfloxacin from aqueous solution.

Multidentate ligands for the synthesis of multi-metallic complexes (2007)
Journal Article
Mustapha, A., Busch, K., Patykiewicz, M., Apedaile, A., Reglinski, J., Kennedy, A. R., & Prior, T. J. (2008). Multidentate ligands for the synthesis of multi-metallic complexes. Polyhedron, 27(2), 868-878. https://doi.org/10.1016/j.poly.2007.11.016

The reaction of the Schiff base species tris-((2-hydroxybenzylidene)aminoethyl)-amine (TrenSal) and tris-((2-hydroxy-5-bromobenzylidene)aminoethyl)amine (Tren5BrSal) with the acetates of nickel and zinc are reported. Two trimetallic complexes (M3L2)... Read More about Multidentate ligands for the synthesis of multi-metallic complexes.

Structural diversity in imidazolidinone organocatalysts: A synchrotron and computational study (2007)
Journal Article
Burley, J. C., Gilmour, R., Prior, T. J., & Day, G. M. (2008). Structural diversity in imidazolidinone organocatalysts: A synchrotron and computational study. Acta Crystallographica Section C: Crystal Structure Communications, 64(1), O10-O14. https://doi.org/10.1107/S0108270107051396

(5)-1-(Methylaminocarbonyl)-3-phenylpropanaminium chloride (52·HCl), C 10 H 15 N 2 O + ·Cl - , crystallizes in the orthorhombic space group P2 1 2 1 2 1 with a single formula unit per asymmetric unit. (5R/S)-5-Benzyl-2,2,3-trimethyl-4-oxoimidazolid... Read More about Structural diversity in imidazolidinone organocatalysts: A synchrotron and computational study.

A synchrotron study of Ba5Ta2Cl2O9 (2007)
Journal Article
Barnes, A. D. J., Francesconi, M. G., & Prior, T. J. (2007). A synchrotron study of Ba5Ta2Cl2O9. Acta Crystallographica Section E: Crystallographic Communications, 63(5), I127 - I128. https://doi.org/10.1107/S1600536807016790

The structure of pentabarium ditantalum dichloride nonaoxide, Ba5Ta2Cl2O9, is isotypic with Ba5Ru1.6W0.4Cl2O9 and with one polymorph of Ba5Ru2Cl2O9. It is related to the perovskite structure and shows a ten-layer stacking of BaO3 and BaCl blocks alon... Read More about A synchrotron study of Ba5Ta2Cl2O9.

Crystal structures, thermogravimetric and magnetic properties of four organodiamine templated vanadium oxide frameworks: influences of diaminoalkane templates (2007)
Journal Article
Settheeworrarit, T., Prior, T. J., Meansiri, S., Limtrakul, J., & Rujiwatra, A. (2008). Crystal structures, thermogravimetric and magnetic properties of four organodiamine templated vanadium oxide frameworks: influences of diaminoalkane templates. Journal of inorganic and organometallic polymers and materials, 18(2), 253-263. https://doi.org/10.1007/s10904-007-9171-y

A series of four diaminoalkane templated vanadium oxide polymeric frameworks, [(V2O8V2O2)-O-IV-O-V](C2H10N2), [V (2O8V2V)-O-IV O-2](C3H12N2), [(V4O10V2V)-O-IV O-4](C4H14N2) and [(V4O102O4)-O-IV-O-V-O-V](C5H16N2), have been successfully prepared under... Read More about Crystal structures, thermogravimetric and magnetic properties of four organodiamine templated vanadium oxide frameworks: influences of diaminoalkane templates.

A versatile family of interconvertible microporous chiral molecular frameworks: The first example of ligand control of network chirality (2000)
Journal Article
Kepert, C. J., Prior, T. J., & Rosseinsky, M. J. (2000). A versatile family of interconvertible microporous chiral molecular frameworks: The first example of ligand control of network chirality. Journal of the American Chemical Society, 122(21), 5158-5168. https://doi.org/10.1021/ja993814s

Two families of molecular frameworks which grow as homochiral single crystals are described. Both consist of multiple interpenetration of the three-connected chiral (10,3)-a (Y*) network and result from the tridentate coordination of the 1,3,5-benzen... Read More about A versatile family of interconvertible microporous chiral molecular frameworks: The first example of ligand control of network chirality.

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