Vanadium-based imido-alkoxide pro-catalysts bearing bisphenolate ligands for ethylene and ε-caprolactone polymerisation
(2009)
Journal Article
Arbaoui, A., Redshaw, C., Homden, D. M., Wright, J. A., & Elsegood, M. R. (2009). Vanadium-based imido-alkoxide pro-catalysts bearing bisphenolate ligands for ethylene and ε-caprolactone polymerisation. Dalton Transactions : an international journal of inorganic chemistry, 8911-8922. https://doi.org/10.1039/b902402f
The pro-catalysts [V(NAr)(L)(OR)] (Ar = p-tolyl, p-ClC6H 4, p-(OMe)C6H4, p-(CF3)C 6H4; R = t-Bu, i-Pr, n-Pr, Et, C(CH3)(CF 3)2) have been prepared in good yields from the reaction of [V(NAr)(OR)3] and the bisphenol 2,2′-CH3CH[4,6- (t-Bu)2C6H2OH]2 (LH... Read More about Vanadium-based imido-alkoxide pro-catalysts bearing bisphenolate ligands for ethylene and ε-caprolactone polymerisation.