All Outputs (1143)

Synthesis and antimicrobial effects of highly dispersed, cellulose-stabilized silver/cellulose nanocomposites (2018)
Journal Article
Alahmadi, N. S., Kelly, S. M., Betts, J. W., Heinze, T., Wadhawan, J. D., & Koschella, A. (2018). Synthesis and antimicrobial effects of highly dispersed, cellulose-stabilized silver/cellulose nanocomposites. RSC advances, 8(7), 3646-3656. https://doi.org/10.1039/c7ra12280b

Small, spherical silver nanoclusters were synthesised on the surface of paper as a model cellulosic fibre substrate by a standard chemical reduction method. The concentration of the silver nanoclusters on the substrate surface is roughly proportional... Read More about Synthesis and antimicrobial effects of highly dispersed, cellulose-stabilized silver/cellulose nanocomposites.

Synthesis of a novel HER2 targeted aza-BODIPY–antibody conjugate: synthesis, photophysical characterisation and in vitro evaluation (2018)
Journal Article
Cheng, M. H. Y., Cheng, M. H., Maruani, A., Savoie, H., Chudasama, V., & Boyle, R. W. (2018). Synthesis of a novel HER2 targeted aza-BODIPY–antibody conjugate: synthesis, photophysical characterisation and in vitro evaluation. Organic & biomolecular chemistry, 16(7), 1144-1149. https://doi.org/10.1039/c7ob02957h

We herein report the synthesis and analysis of a novel aza-BODIPY–antibody conjugate, formed by controlled and regioselective bioconjugation methodology. Employing the clinically relevant antibody, which targets HER2 positive cancers, represents the... Read More about Synthesis of a novel HER2 targeted aza-BODIPY–antibody conjugate: synthesis, photophysical characterisation and in vitro evaluation.

Smart soaps: stimulus responsive soap–hydrogel bead composites for controlled dissolution and release of actives (2018)
Journal Article
Thompson, B. R., Rutkevičius, M., Horozov, T. S., Stoyanov, S. D., & Paunov, V. N. (2018). Smart soaps: stimulus responsive soap–hydrogel bead composites for controlled dissolution and release of actives. Materials Chemistry Frontiers, 2(2), 402-409. https://doi.org/10.1039/c7qm00556c

We designed pressure responsive soap–hydrogel bead composites by incorporating agar hydrogel beads of different size distributions within a molten soap matrix at various volume fractions. Upon cooling, the combined suspension of hydrogel beads into t... Read More about Smart soaps: stimulus responsive soap–hydrogel bead composites for controlled dissolution and release of actives.

Host-guest interaction of cucurbit[8]uril with n-(3-aminopropyl)cyclohexylamine: Cyclohexyl encapsulation triggered ternary complex (2018)
Journal Article
Xia, Y., Wang, C.-Z., Tian, M., Tao, Z., Ni, X.-L., Prior, T. J., & Redshaw, C. (2018). Host-guest interaction of cucurbit[8]uril with n-(3-aminopropyl)cyclohexylamine: Cyclohexyl encapsulation triggered ternary complex. Molecules, 23(1), 175. https://doi.org/10.3390/molecules23010175

2018 by the authors. The host-guest interaction of a series of cyclohexyl-appended guests with cucurbit[8]uril (Q[8] ) was studied by 1 H NMR spectroscopy, isothermal titration calorimetry (ITC), and X-ray crystallography. The X-ray structure reveale... Read More about Host-guest interaction of cucurbit[8]uril with n-(3-aminopropyl)cyclohexylamine: Cyclohexyl encapsulation triggered ternary complex.

Multiple photoluminescence from pyrene-fused hexaarylbenzenes with aggregation-enhanced emission features (2018)
Journal Article
Venkatesan, P., Yamato, T., Elsegood, M. R., Wang, C.-Z., Noda, Y., Wu, C., Feng, X., Venatesan, P., Cong, H., Elsegood, M. R. J., Warwick, T. G., Teat, S. J., Redshaw, C., & Yamato, P. T. (2018). Multiple photoluminescence from pyrene-fused hexaarylbenzenes with aggregation-enhanced emission features. Asian journal of organic chemistry an ACES journal, 7(2), 444-450. https://doi.org/10.1002/ajoc.201700563

© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Multiple photoluminescence, which included monomer emission, excimer emission, and charge-transfer emission processes, has been observed from new pyrene-fused hexaarylbenzene (HAB) compounds, which... Read More about Multiple photoluminescence from pyrene-fused hexaarylbenzenes with aggregation-enhanced emission features.

Pyrene-based color-tunable dipolar molecules: Synthesis, characterization and optical properties (2018)
Journal Article
Wang, C. Z., Feng, X., Kowser, Z., Wu, C., Akther, T., Elsegood, M. R. J., Redshaw, C., & Yamato, T. (2018). Pyrene-based color-tunable dipolar molecules: Synthesis, characterization and optical properties. Dyes and pigments : an international journal, 153, 125-131. https://doi.org/10.1016/j.dyepig.2018.01.003

© 2018 Elsevier Ltd A controllable regioselective approach to achieve dipolar functionalization at the active sites (1,3-positions) and K-region (5,9-positions) of pyrene is demonstrated. Following this strategy, a set of dipolar 1,3-diphenyl-5,9-di(... Read More about Pyrene-based color-tunable dipolar molecules: Synthesis, characterization and optical properties.

Solution-processable, niobium-doped titanium oxide nanorods for application in low-voltage, large-area electronic devices (2017)
Journal Article
Alharthi, F. A., Cheng, F., Verrelli, E., Kemp, N. T., Lee, A. F., Isaacs, M. A., O’Neill, M., & Kelly, S. M. (2017). Solution-processable, niobium-doped titanium oxide nanorods for application in low-voltage, large-area electronic devices. Journal of Materials Chemistry C, 6(5), 1038-1047. https://doi.org/10.1039/c7tc04197g

We report for the first time the one-step synthesis of solution-processable, highly crystalline, niobiumdoped titanium dioxide (Nb-TiO2) nanorods in the anatase phase by the hydrolytic condensation of Ti(OiPr)4 and niobium(V) ethoxide using oleic aci... Read More about Solution-processable, niobium-doped titanium oxide nanorods for application in low-voltage, large-area electronic devices.

Surface-active hollow titanosilicate particles as a Pickering interfacial catalyst for liquid-phase alkene epoxidation reactions (2017)
Journal Article
Lv, G., Wang, F., Zhang, X., & Binks, B. P. (2018). Surface-active hollow titanosilicate particles as a Pickering interfacial catalyst for liquid-phase alkene epoxidation reactions. Langmuir : the ACS journal of surfaces and colloids, 34(1), 302-310. https://doi.org/10.1021/acs.langmuir.7b03633

Design of catalyst particles bearing excellent catalytic activity and suitable surface wettability is the key to the successful application of Pickering interfacial catalysis. In this study, the epoxidation of 1-hexene and cyclohexene with aqueous hy... Read More about Surface-active hollow titanosilicate particles as a Pickering interfacial catalyst for liquid-phase alkene epoxidation reactions.

23-electron octahedral molybdenum cluster complex [{Mo 6 I 8 }Cl 6 ] – (2017)
Journal Article
Syrokvashin, M. M., Vorotnikova, N. A., Vorotnikov, Y. A., Novozhilov, I. N., Syrokvashin, M. М., Nadolinny, V. A., Kuratieva, N. V., Benoit, D. M., Mironov, Y. V., Walton, R. I., Clarkson, G. J., Kitamura, N., Sutherland, A. J., Shestopalov, M. A., & Efremova, O. A. (2018). 23-electron octahedral molybdenum cluster complex [{Mo 6 I 8 }Cl 6 ] –. Inorganic chemistry, 57(2), https://doi.org/10.1021/acs.inorgchem.7b02760

Photoactive transition metal compounds that are prone to reversible redox reactions are important for myriad applications, including catalysis, optoelectronics and sensing. This article describes chemical and electro-chemical methods to prepare clust... Read More about 23-electron octahedral molybdenum cluster complex [{Mo 6 I 8 }Cl 6 ] –.

Lipase immobilised on silica monoliths as continuous-flow microreactors for triglyceride transesterification (2017)
Journal Article
Alotaibi, M., Manayil, J. C., Greenway, G. M., Haswell, S. J., Kelly, S. M., Lee, A. F., Wilson, K., & Kyriakou, G. (2017). Lipase immobilised on silica monoliths as continuous-flow microreactors for triglyceride transesterification. Reaction Chemistry and Engineering, 3(1), 68-74. https://doi.org/10.1039/c7re00162b

Lipase immobilised on silica monoliths has been prepared and applied as biocatalytic continuous-flow microreactors for the transesterification of tributyrin as a model bio-oil component. Candida antarctica lipase was trapped within the pores of silic... Read More about Lipase immobilised on silica monoliths as continuous-flow microreactors for triglyceride transesterification.

Capillary structured suspensions from in situ hydrophobized calcium carbonate particles suspended in a polar liquid media (2017)
Journal Article
Dunstan, T. S., Das, A. A. K., Starck, P., Stoyanov, S. D., & Paunov, V. N. (2018). Capillary structured suspensions from in situ hydrophobized calcium carbonate particles suspended in a polar liquid media. Langmuir : the ACS journal of surfaces and colloids, 34(1), 442-452. https://doi.org/10.1021/acs.langmuir.7b03589

© 2017 American Chemical Society. We demonstrate that capillary suspensions can be formed from hydrophilic calcium carbonate particles suspended in a polar continuous media and connected by capillary bridges formed of minute amounts of an immiscible... Read More about Capillary structured suspensions from in situ hydrophobized calcium carbonate particles suspended in a polar liquid media.

Reduction of phenylacetylenes using Raney Ni-Al alloy, Al powder in the presence of noble metal catalysts in water (2017)
Journal Article
Rayhan, U., Kowser, Z., Islam, M. N., Redshaw, C., & Yamato, T. (2017). Reduction of phenylacetylenes using Raney Ni-Al alloy, Al powder in the presence of noble metal catalysts in water. Arkivoc, 2018(2), 241-251. https://doi.org/10.24820/ark.5550190.p010.277

Dedicated to Prof. Kenneth Laali on the occasion of his 66th birthday Received mm-dd-yyyy Accepted mm-dd-yyyy Published on line mm-dd-yyyy Dates to be inserted by editorial office Abstract The chemoselective reduction is based on the reaction of Rane... Read More about Reduction of phenylacetylenes using Raney Ni-Al alloy, Al powder in the presence of noble metal catalysts in water.

Emulsion stabilisation by complexes of oppositely charged synthetic polyelectrolytes (2017)
Journal Article
Bago Rodriguez, A. M., Binks, B. P., & Sekine, T. (2018). Emulsion stabilisation by complexes of oppositely charged synthetic polyelectrolytes. Soft matter, 14(2), 239-254. https://doi.org/10.1039/c7sm01845b

We investigate the possibility of stabilising oil-water emulsions from the polyelectrolyte complexes (PEC) obtained in mixtures of a strong cationic polyelectrolyte (poly(diallyldimethylammonium chloride), PDADMAC) and a weak anionic one (poly(acryli... Read More about Emulsion stabilisation by complexes of oppositely charged synthetic polyelectrolytes.

Assembly of high-potency photosensitizer-antibody conjugates through application of dendron multiplier technology (2017)
Journal Article
Rodrigues, J. M., Cheng, M. H., Bryden, F., Maruani, A., Rodrigues, J. M. M., Cheng, M. H. Y., Savoie, H., Beeby, A., Chudasama, V., & Boyle, R. W. (2018). Assembly of high-potency photosensitizer-antibody conjugates through application of dendron multiplier technology. Bioconjugate chemistry, 29(1), 176-181. https://doi.org/10.1021/acs.bioconjchem.7b00678

© 2017 American Chemical Society. Exploitation of photosensitizers as payloads for antibody-based anticancer therapeutics offers a novel alternative to the small pool of commonly utilized cytotoxins. However, existing bioconjugation methodologies are... Read More about Assembly of high-potency photosensitizer-antibody conjugates through application of dendron multiplier technology.

Thermally responsive capillary suspensions (2017)
Journal Article
Das, A. A., Dunstan, T. S., Stoyanov, S. D., Starck, P., & Paunov, V. N. (2017). Thermally responsive capillary suspensions. ACS Applied Materials & Interfaces, 9(50), 44152-44160. https://doi.org/10.1021/acsami.7b11358

© 2017 American Chemical Society. We demonstrate that stimulus-responsive capillary-structured materials can be formed from hydrophobized calcium carbonate particles suspended in a non-polar phase (silicone oil) and bridged by very small amounts of a... Read More about Thermally responsive capillary suspensions.

Synthesis and structure of a chiral areno-bridged [2.4]metacyclophane (2017)
Journal Article
Islam, M., Akther, T., Matsumoto, T., Tanaka, J., Thuéry, P., Redshaw, C., & Yamato, T. (2018). Synthesis and structure of a chiral areno-bridged [2.4]metacyclophane. Tetrahedron, 74(2), 329-335. https://doi.org/10.1016/j.tet.2017.11.075

© 2017 Elsevier Ltd The reductive coupling reaction of 1,4-bis(3-acetyl-5-tert-butyl-2-methoxyphenyl)butane 3 was carried out using TiCl 4 -Zn in pyridine followed by a McMurry coupling reaction to afford the compounds anti and syn 1,2-dimethyl[2.4]M... Read More about Synthesis and structure of a chiral areno-bridged [2.4]metacyclophane.

Molybdocalix[4]arene N,O-Schiff-base ligands (2017)
Journal Article
Wang, X., Zhao, K. Q., Elsegood, M. R., & Redshaw, C. (2018). Molybdocalix[4]arene N,O-Schiff-base ligands. Supramolecular chemistry, 30(5-6), 404-410. https://doi.org/10.1080/10610278.2017.1403608

The ‘one-pot’ reaction of 2-hydroxy-3,5-di-tert-butylsalicylaldehyde with in situ generated ‘amino calixarene’ (from {Mo[(2-NC 6 H 4 ) 2 CH 2 CH 2 ]Cl 2 (DME)}, KOtBu and p-tert-butylcalix[4]areneH 4 LH 4 ) afforded, after work-up, the heterobimetall... Read More about Molybdocalix[4]arene N,O-Schiff-base ligands.

Nucleosome acidic patch-targeting binuclear ruthenium compounds induce aberrant chromatin condensation (2017)
Journal Article
Davey, G. E., Dyson, P. J., Davey, C. A., Davey, G., Adhireksan, Z., Ma, Z., Riedel, T., Sharma, D., Padavattan, S., Rhodes, D., Ludwig, A., Sandin, S., Murray, B. S., Dyson, P., & Davey, C. (2017). Nucleosome acidic patch-targeting binuclear ruthenium compounds induce aberrant chromatin condensation. Nature communications, 8(1), Article 1575. https://doi.org/10.1038/s41467-017-01680-4

© 2017 The Author(s). The 'acidic patch' is a highly electronegative cleft on the histone H2A-H2B dimer in the nucleosome. It is a fundamental motif for protein binding and chromatin dynamics, but the cellular impact of targeting this potentially the... Read More about Nucleosome acidic patch-targeting binuclear ruthenium compounds induce aberrant chromatin condensation.

Amino acid based gallium-68 chelators capable of radiolabeling at neutral pH (2017)
Journal Article
Kubicek, V., Bohmova, Z., Price, T. W., Gallo, J., Kubíček, V., Böhmová, Z., Prior, T. J., Greenman, J., Hermann, P., & Stasiuk, G. J. (2017). Amino acid based gallium-68 chelators capable of radiolabeling at neutral pH. Dalton Transactions : an international journal of inorganic chemistry, 46(48), 16973-16982. https://doi.org/10.1039/c7dt03398b

Gallium-68 ( 68 Ga) has been the subject of increasing interest for its potential in the production of radiotracers for diagnosis of diseases. In this work we report the complexation of 68 Ga by the amino acid based tripodal chelate H 3 Dpaa, and two... Read More about Amino acid based gallium-68 chelators capable of radiolabeling at neutral pH.

Characterization of the Submicrometer Hierarchy Levels in the Twist-Bend Nematic Phase with Nanometric Helices via Photopolymerization. Explanation for the Sign Reversal in the Polar Response (2017)
Journal Article
Panov, V. P., Sreenilayam, S. P., Panarin, Y. P., Vij, J. K., Welch, C. J., & Mehl, G. H. (2017). Characterization of the Submicrometer Hierarchy Levels in the Twist-Bend Nematic Phase with Nanometric Helices via Photopolymerization. Explanation for the Sign Reversal in the Polar Response. Nano Letters, 17(12), 7515-7519. https://doi.org/10.1021/acs.nanolett.7b03441

Photopolymerization of a reactive mesogen mixed with a mesogenic dimer, shown to exhibit the twist-bend nematic phase (NTB), reveals the complex structure of the self-deformation patterns observed in planar cells. The polymerized reactive mesogen ret... Read More about Characterization of the Submicrometer Hierarchy Levels in the Twist-Bend Nematic Phase with Nanometric Helices via Photopolymerization. Explanation for the Sign Reversal in the Polar Response.