An ethylene cross-bridged pentaazamacrocycle and its Cu2+ complex: constrained ligand topology and excellent kinetic stability

Shircliff, Anthony D.; Burke, Benjamin P.; Davilla, Dustin J.; Burgess, Gwendolyn E.; Okorocha, Faith A.; Shrestha, Alina; Allbritton, Elisabeth M. A.; Nguyen, Phillip T.; Lamar, Rachael L.; Jones, Donald G.; Gorbet, Michael Joseph; Allen, Michael B.; Eze, John I.; Fernandez, Andrea T.; Ramirez, Daniel; Archibald, Stephen J.; Prior, Timothy J.; Krause, Jeanette A.; Oliver, Allen G.; Hubin, Timothy J.

Abstract

Rigid and topologically constrained ethylene cross-bridged tetraazamacrocycles have been increasingly utilised for thirty years as they form remarkably stable transition metal complexes for catalysis, biomedical imaging, and inorganic drug molecule applications. Extending these benefits to pentaazamacrocycles has been achieved and a first transition metal complex prepared and structurally characterized. This journal is

Citation

Shircliff, A. D., Burke, B. P., Davilla, D. J., Burgess, G. E., Okorocha, F. A., Shrestha, A., …Hubin, T. J. (2020). An ethylene cross-bridged pentaazamacrocycle and its Cu2+ complex: constrained ligand topology and excellent kinetic stability. Chemical communications : Chem comm / the Royal Society of Chemistry, 56(54), 7519-7522. https://doi.org/10.1039/d0cc00919a

• Journal Article Type: Article
• Acceptance Date: Jun 1, 2020
• Online Publication Date: Jun 2, 2020
• Publication Date: Jul 11, 2020
• Deposit Date: Jun 13, 2020
• Publicly Available Date: Jun 3, 2021
• Journal: Chemical Communications
• Print ISSN: 1359-7345
• Electronic ISSN: 1364-548X
• Publisher: Royal Society of Chemistry
• Peer Reviewed: Peer Reviewed
• Volume: 56
• Issue: 54
• Pages: 7519-7522
• DOI: https://doi.org/10.1039/d0cc00919a
• Keywords: Materials Chemistry; Electronic, Optical and Magnetic Materials; General Chemistry; Surfaces, Coatings and Films; Metals and Alloys; Ceramics and Composites; Catalysis
• Public URL: https://hull-repository.worktribe.com/output/3520880
• Publisher URL: https://pubs.rsc.org/en/content/articlelanding/2020/CC/D0CC00919A#!divAbstract
• Additional Information: : This document is Similarity Check deposited; : Supplementary Information; : Crystal Structure Data; : Michael B. Allen (ORCID); : Stephen J. Archibald (ORCID); : Stephen J. Archibald (ResearcherID); : Timothy J. Hubin (ORCID); : Timothy J. Hubin (ResearcherID); : Authors can choose between single-blind and double-blind peer review; : Received 5 February 2020; Accepted 1 June 2020; Accepted Manuscript published 2 June 2020; Advance Article published 8 June 2020