Sequestration of edible oil from emulsions using new single and double layered microcapsules from plant spores

Diego-Taboada, Alberto; Cousson, Priscille; Raynaud, Elodie; Huang, Youkui; Lorch, M.; Binks, B.P.; Queneau, Yves; Boa, Andrew N.; Atkin, Stephen L.; Diego Taboada, Alberto; Beckett, Stephen T.; Mackenzie, Grahame; Boa, Andrew

doi:10.1039/c2jm00103a

Authors

Alberto Diego-Taboada

Priscille Cousson

Elodie Raynaud

Youkui Huang

Professor Mark Lorch M.Lorch@hull.ac.uk
Professor of Public Engagement and Science Communication. Interim Head of Department for Chemistry, Biochemistry and Chemical Engineering

Professor Bernard P Binks B.P.Binks@hull.ac.uk
Professor of Physical Chemistry

Yves Queneau

Dr Andrew Boa A.N.Boa@hull.ac.uk
Senior Lecturer

Stephen L. Atkin

Alberto Diego Taboada A.D.Taboada@hull.ac.uk

Stephen T. Beckett

Grahame Mackenzie G.Mackenzie@hull.ac.uk

Dr Andrew Boa A.N.Boa@hull.ac.uk
Senior Lecturer

Abstract

Microcapsules were obtained conveniently from Lycopodium clavatum spores possessing either a single layered shell of sporopollenin (exine) or double layered shell of sporopollenin and cellulose with an inner layer (intine). These microcapsules were further modified by converting their surface hydroxyl groups (alcohols, phenols carboxylic acids) into salts (Na+and K+), acetates and methyl ethers accordingly. All of these new types of microcapsules were found to sequester efficiently edible oils from oil-in-water emulsions with the acetylated forms being the most efficient to sequester oils in near quantitative fashion. The latter could be recycled without losing efficiency to recover oil. Oils could also be released from the microcapsules in a stepwise manner by repeated rubbing.

Citation

Queneau, Y., Boa, A., Atkin, S., Beckett, S., MacKenzie, G., Huang, Y., …Mackenzie, G. (2012). Sequestration of edible oil from emulsions using new single and double layered microcapsules from plant spores. Journal of Materials Chemistry, 22(19), 9767-9773. https://doi.org/10.1039/c2jm00103a

Journal Article Type	Article
Acceptance Date	Mar 19, 2012
Online Publication Date	Apr 12, 2012
Publication Date	Apr 21, 2012
Publicly Available Date
Journal	Journal of Materials Chemistry
Print ISSN	0959-9428
Electronic ISSN	1364-5501
Publisher	Royal Society of Chemistry
Peer Reviewed	Peer Reviewed
Volume	22
Issue	19
Pages	9767-9773
DOI	https://doi.org/10.1039/c2jm00103a
Keywords	Materials Chemistry; General Chemistry
Public URL	https://hull-repository.worktribe.com/output/424052
Publisher URL	https://www.scopus.com/inward/record.uri?eid=2-s2.0-84860381272&doi=10.1039%2fc2jm00103a&partnerID=40&md5=d0788c16a656fd152c44ad1f41fc6b22