Synthesis and Structures of [2.n]Metacyclophan-1-enes and their Conversion to Highly Strained [2.n]Metacyclophane-1-ynes
(2020)
Journal Article
Akther, T., Islam, M. M., Kowser, Z., Matsumoto, T., Tanaka, J., Rahman, S., Alodhayb, A., Georghiou, P. E., Redshaw, C., & Yamato, T. (2020). Synthesis and Structures of [2.n]Metacyclophan-1-enes and their Conversion to Highly Strained [2.n]Metacyclophane-1-ynes. European Journal of Organic Chemistry, 2020(27), 4167-4175. https://doi.org/10.1002/ejoc.202000548
Syn-[2.n]metacyclophan-1-enes (n=5, 6, 8) are synthesized by the McMurry cyclization of 1,n-bis(3-formyl-4-methoxyphenyl)alkanes in good yields. Syn-[2.n]metacyclophan-1-enes (n= 6, 8) were converted to the highly strained syn-type [2.n] metacyclopha... Read More about Synthesis and Structures of [2.n]Metacyclophan-1-enes and their Conversion to Highly Strained [2.n]Metacyclophane-1-ynes.