All Outputs (1148)

Porphyrin-nanosensor conjugates. New tools for the measurement of intracellular response to reactive oxygen species (2010)
Journal Article
Josefsen, L. B., Aylott, J. W., Beeby, A., Warburton, P., Boyle, J. P., Peers, C., & Boyle, R. W. (2010). Porphyrin-nanosensor conjugates. New tools for the measurement of intracellular response to reactive oxygen species. Photochemical & photobiological sciences : an international journal, 9(6), 801-811. https://doi.org/10.1039/c0pp00004c

Reactive oxygen species (ROS) have for some time been implicated in the onset and progression of medical conditions including cancer, ageing, heart disease and Alzheimer's disease. Recently, it has been postulated that ROS play a much more subtle rol... Read More about Porphyrin-nanosensor conjugates. New tools for the measurement of intracellular response to reactive oxygen species.

Ionothermal synthesis and crystal structures of metal phosphate chains (2010)
Journal Article
Wragg, D. S., Le Ouay, B., Beale, A. M., O'Brien, M. G., Slawin, A. M., Warren, J. E., Prior, T. J., & Morris, R. E. (2010). Ionothermal synthesis and crystal structures of metal phosphate chains. Journal of Solid State Chemistry, 183(7), 1625-1631. https://doi.org/10.1016/j.jssc.2010.05.002

We have prepared isostructural aluminium and gallium phosphate chains by ionothermal reactions in 1-ethyl-3-methylimidazolium bromide and 1-ethylpyridinium bromide under a variety of conditions. The chains can be prepared as pure phases or along with... Read More about Ionothermal synthesis and crystal structures of metal phosphate chains.

One-step photoembossing for submicrometer surface relief structures in liquid crystal semiconductors (2010)
Journal Article
Liedtke, A., Lei, C., O’Neill, M., Dyer, P. E., Kitney, S. P., & Kelly, S. M. (2010). One-step photoembossing for submicrometer surface relief structures in liquid crystal semiconductors. ACS Nano, 4(6), 3248-3253. https://doi.org/10.1021/nn100012g

We report a new single-step method to directly imprint nanometer-scale structures on photoreactive organic semiconductors. A surface relief grating is spontaneously formed when a light-emitting, liquid crystalline, and semiconducting thin film is irr... Read More about One-step photoembossing for submicrometer surface relief structures in liquid crystal semiconductors.

Rapid PCR amplification using a microfluidic device with integrated microwave heating and air impingement cooling (2010)
Journal Article
Shaw, K. J., Docker, P. T., Yelland, J. V., Dyer, C. E., Greenman, J., Greenway, G. M., & Haswell, S. J. (2010). Rapid PCR amplification using a microfluidic device with integrated microwave heating and air impingement cooling. Lab on a chip, 10(13), 1725-1728. https://doi.org/10.1039/c000357n

A microwave heating system is described for performing polymerase chain reaction (PCR) in a microfluidic device. The heating system, in combination with air impingement cooling, provided rapid thermal cycling with heating and cooling rates of up to 6... Read More about Rapid PCR amplification using a microfluidic device with integrated microwave heating and air impingement cooling.

Influence of nanoparticle addition to Winsor surfactant microemulsion systems (2010)
Journal Article
Binks, B., Fletcher, P., & Tian, L. (2010). Influence of nanoparticle addition to Winsor surfactant microemulsion systems. Colloids and surfaces. A, Physicochemical and engineering aspects, 363(1-3), 8-15. https://doi.org/10.1016/j.colsurfa.2010.03.045

The influence of adding negatively charged silica nanoparticles to multiphase Winsor microemulsion systems of cationic surfactant/alcohol cosurfactant is reported. It is found that the particles do not change the salt-induced progression of Winsor sy... Read More about Influence of nanoparticle addition to Winsor surfactant microemulsion systems.

Vanadium procatalysts bearing chelating aryloxides: Structure-activity trends in ethylene polymerisation (2010)
Journal Article
Redshaw, C. (2010). Vanadium procatalysts bearing chelating aryloxides: Structure-activity trends in ethylene polymerisation. Dalton Transactions : an international journal of inorganic chemistry, 39(24), 5595-5604. https://doi.org/10.1039/b924088h

High-valent vanadium complexes bearing a variety of chelating aryloxides including di- and linear tri-phenolates, C/N-capped tripods, phenoxyimines and calixarenes type ligands, when used in combination with dialkylaluminium halides as co-catalyst an... Read More about Vanadium procatalysts bearing chelating aryloxides: Structure-activity trends in ethylene polymerisation.

The development and evaluation of a conducting matrix for the electrochemical regeneration of the immobilised co-factor NAD(H) under continuous flow (2010)
Journal Article
Ngamsom, B., Hickey, A. M., Greenway, G. M., Littlechild, J. A., McCreedy, T., Watts, P., & Wiles, C. (2010). The development and evaluation of a conducting matrix for the electrochemical regeneration of the immobilised co-factor NAD(H) under continuous flow. Organic & biomolecular chemistry, 8(10), 2419-2424. https://doi.org/10.1039/b924100k

Through the preparation of a novel controlled pore glass-poly(pyrrole) material we have developed a conducting support that is not only suitable for the co-immobilisation of enzymes and co-factors, but also enables the facile electrochemical regenera... Read More about The development and evaluation of a conducting matrix for the electrochemical regeneration of the immobilised co-factor NAD(H) under continuous flow.

Hydrogen bonded dimers vs. one-dimensional chains in 2-thiooxoimidazolidin-4-one (thiohydantoin) drug derivatives (2010)
Journal Article
Jha, S., Silversides, J. D., Boyle, R. W., & Archibald, S. J. (2010). Hydrogen bonded dimers vs. one-dimensional chains in 2-thiooxoimidazolidin-4-one (thiohydantoin) drug derivatives. CrystEngComm RSC, 12(6), 1730-1739. https://doi.org/10.1039/b924683e

Hydantoins have been known as medicinally active compounds since the 1940s and thiohydantoin derivatives are currently undergoing clinical trials as potent androgen receptor antagonist drugs. Control of solid state properties including the formation... Read More about Hydrogen bonded dimers vs. one-dimensional chains in 2-thiooxoimidazolidin-4-one (thiohydantoin) drug derivatives.

Observation and isolation of layered and framework ytterbium hydroxide phases using in situ energy-dispersive X-ray diffraction (2010)
Journal Article
McIntyre, L. J., Prior, T. J., & Fogg, A. M. (2010). Observation and isolation of layered and framework ytterbium hydroxide phases using in situ energy-dispersive X-ray diffraction. Chemistry of materials : a publication of the American Chemical Society, 22(8), 2635-2645. https://doi.org/10.1021/cm1000208

In situ energy-dispersive X-ray diffraction has been used to investigate the synthesis of the recently reported lanthanide hydroxynitrate phases, Ln 2 (OH) 5 NO 3 ·1.5H 2 O (Ln = Y, Er, Yb). Through control of the reaction temperature, three distinct... Read More about Observation and isolation of layered and framework ytterbium hydroxide phases using in situ energy-dispersive X-ray diffraction.

Non-aqueous foams in lubricating oil systems (2010)
Journal Article
Binks, B., Davies, C., Fletcher, P., & Sharp, E. (2010). Non-aqueous foams in lubricating oil systems. Colloids and surfaces. A, Physicochemical and engineering aspects, 360(1-3), 198-204. https://doi.org/10.1016/j.colsurfa.2010.02.028

We have investigated the foaming properties of mixtures of a hydrocarbon oil solvent with various low molar mass, polymeric and overbased detergent particle additives used in lubricating oils. Foam formation occurs only when the additive concentratio... Read More about Non-aqueous foams in lubricating oil systems.

The dramatic influence of the location of bend and of lateral fluoro substitution on the mesomorphic properties of angular chiral esters based on a 1,3-disubstituted benzene ring (2010)
Journal Article
Fergusson, K. M., & Hird, M. (2010). The dramatic influence of the location of bend and of lateral fluoro substitution on the mesomorphic properties of angular chiral esters based on a 1,3-disubstituted benzene ring. Journal of Materials Chemistry, 20(15), 3069-3078. https://doi.org/10.1039/b923267b

The synthesis and mesomorphic properties of a range of 3-ring and 4-ring chiral esters based on a 1,3-disubstituted benzene unit are detailed. These materials all deviate from the usual linear molecular architecture of liquid crystals, and hence are... Read More about The dramatic influence of the location of bend and of lateral fluoro substitution on the mesomorphic properties of angular chiral esters based on a 1,3-disubstituted benzene ring.

Access to a primary aminosporopollenin solid support from plant spores (2010)
Journal Article
Barrier, S., Löbbert, A., Boasman, A. J., Boa, A. N., Lorch, M., Atkin, S. L., & MacKenzie, G. (2010). Access to a primary aminosporopollenin solid support from plant spores. Green chemistry : an international journal and green chemistry resource : GC, 12(2), 234-240. https://doi.org/10.1039/b913215e

Sporopollenin, which is a naturally occurring and highly resilient organic polymer constituting the external shell of spores and pollen grains, has been converted into a primary amine form with a loading of 0.58 +/- 0.04 mmol. g(-1) by reductive amin... Read More about Access to a primary aminosporopollenin solid support from plant spores.

Viscoelastic properties of silica nanoparticle monolayers at the air-water interface (2010)
Journal Article
Zang, D. Y., Rio, E., Langevin, D., Wei, B., & Binks, B. P. (2010). Viscoelastic properties of silica nanoparticle monolayers at the air-water interface. European Physical Journal E, 31(2), 125-134. https://doi.org/10.1140/epje/i2010-10565-7

We have investigated the rheological behaviour of silica nanoparticle layers at the air-water interface. Both compressed and deposited layers have been studied in Langmuir troughs and with a bicone rheometer. The compressed layers are more homogeneou... Read More about Viscoelastic properties of silica nanoparticle monolayers at the air-water interface.

Rapid, multistep on-chip DNA hybridisation in continuous flow on magnetic particles (2010)
Journal Article
Vojtíšek, M., Iles, A., & Pamme, N. (2010). Rapid, multistep on-chip DNA hybridisation in continuous flow on magnetic particles. Biosensors & bioelectronics, 25(9), 2172-2176. https://doi.org/10.1016/j.bios.2010.01.034

DNA hybridisation is an important tool for bioanalytical research and clinical diagnostics; conventional methods, however, require long incubation times and numerous washing steps, rendering the procedure time consuming and labour intensive. In this... Read More about Rapid, multistep on-chip DNA hybridisation in continuous flow on magnetic particles.

The structure of the antioxidant 2,3,4-trihydroxybenzoic acid dihydrate (2010)
Journal Article
Sharp, A. J., & Prior, T. J. (2010). The structure of the antioxidant 2,3,4-trihydroxybenzoic acid dihydrate. Journal of chemical crystallography, 40(7), 630-633. https://doi.org/10.1007/s10870-010-9708-8

The structure of 2,3,4-trihydroxybenzoic acid dihydrate has been determined at 120 K from a twinned crystal. The compound crystallizes in the centrosymmetric space group P1̄ with Z = 2 and unit cell parameters a = 6.6165(14), b = 7.2341(14), c = 9.71... Read More about The structure of the antioxidant 2,3,4-trihydroxybenzoic acid dihydrate.

Magnetic ordering in nitrides with the η-carbide structure, (Ni,Co,Fe)2(Ga,Ge)Mo3N (2010)
Journal Article
Sviridov, L. A., Battle, P. D., Grandjean, F., Long, G. J., & Prior, T. J. (2010). Magnetic ordering in nitrides with the η-carbide structure, (Ni,Co,Fe)2(Ga,Ge)Mo3N. Inorganic chemistry, 49(3), 1133-1143. https://doi.org/10.1021/ic902069w

Compositions in the series Ni2-xCoxGeMO3N (0 <= x <= 2.), Co2Ge1-xGaxMo3N (0 < x <= 0.7.), Co2-xFexGeMo3N (0 <= x <= 2), and Co2-xFexGe0.5Ga0.5Mo3N (0 <= x <= 0.8) have been synthesized by the reductive nitridation of binary oxides and studied by app...

Iron(III) and Zinc(II) calixarene complexes: Synthesis, structural studies, and use as procatalysts for ε-caprolactone polymerization (2010)
Journal Article
Arbaoui, A., Redshaw, C., Elsegood, M. R. J., Wright, V. E., Yoshizawa, A., & Yamato, T. (2010). Iron(III) and Zinc(II) calixarene complexes: Synthesis, structural studies, and use as procatalysts for ε-caprolactone polymerization. Chemistry - An Asian Journal, 5(3), 621-633. https://doi.org/10.1002/asia.200900514

Treatment of the heterobimetallic iron(II) alkoxides [(THF)MFe(OtBu)3]2 with p-tert-butylcalix[4]areneH4 (L1H4) affords the oxo-bridged diiron(III) complexes {Fe[M(NCMe)x]2L1}2(μ-O), M=Na, x=2 1⋅8(CH3CN), M= K, x=3 2⋅3.5(CH3CN); similar use of p-tert... Read More about Iron(III) and Zinc(II) calixarene complexes: Synthesis, structural studies, and use as procatalysts for ε-caprolactone polymerization.

Shearing particle monolayers: Strain-rate frequency superposition (2010)
Journal Article
Zang, D., Langevin, D., Binks, B. P., & Wei, B. (2010). Shearing particle monolayers: Strain-rate frequency superposition. Physical review. E, Statistical, nonlinear, and soft matter physics, 81(1), 011604. https://doi.org/10.1103/PhysRevE.81.011604

We report surface shear rheological measurements on monolayers of silica nanoparticles at the air-water interface. We have used the method of strain-rate frequency superposition (SRFS) to characterize the structural relaxation. We show that the rheol... Read More about Shearing particle monolayers: Strain-rate frequency superposition.

Site-specific and stoichiometric conjugation of cationic porphyrins to antiangiogenic monoclonal antibodies (2010)
Journal Article
Alonso, C. M. A., Palumbo, A., Bullous, A. J., Pretto, F., Neri, D., & Boyle, R. W. (2010). Site-specific and stoichiometric conjugation of cationic porphyrins to antiangiogenic monoclonal antibodies. Bioconjugate chemistry, 21(2), 302-313. https://doi.org/10.1021/bc9003537

Synthesis of three new cationic thiol-reactive maleimide-porphyrin derivatives and their use in site-specific conjugation to monoclonal antibodies is reported. The selective reactivity toward thiols is demonstrated using competition experiments, wher... Read More about Site-specific and stoichiometric conjugation of cationic porphyrins to antiangiogenic monoclonal antibodies.

Desymmetrisation of (4R,5S)-4,5-diphenylimidazolidine-2-thione using pentafluorophenyl active esters (2010)
Journal Article
Andreou, A., Eames, J., Motevalli, M., Prior, T. J., & Watkinson, M. (2010). Desymmetrisation of (4R,5S)-4,5-diphenylimidazolidine-2-thione using pentafluorophenyl active esters. Tetrahedron letters; the international organ for the rapid publication of preliminary communications in organic chemistry, 51(10), 1423-1425. https://doi.org/10.1016/j.tetlet.2010.01.019

(4R,5S)-4,5-Diphenylimidazolidine-2-thione is efficiently desymmetrised by stereorandom deprotonation with NaHMDS, followed by kinetic resolution of the resulting racemic intermediate with an enantiomerically pure pentafluorophenyl active ester. The... Read More about Desymmetrisation of (4R,5S)-4,5-diphenylimidazolidine-2-thione using pentafluorophenyl active esters.