Professor Bernie Binks' Outputs (152)

Novel oil-in-water emulsions stabilised by ionic surfactant and similarly charged nanoparticles at very low concentrations (2018)
Journal Article
Xu, M., Jiang, J., Pei, X., Song, B., Cui, Z., & Binks, B. P. (2018). Novel oil-in-water emulsions stabilised by ionic surfactant and similarly charged nanoparticles at very low concentrations. Angewandte Chemie, 57(26), 7738-7742. https://doi.org/10.1002/anie.201802266

Novel oil-in-water (O/W) emulsions are prepared which are stabilised by a cationic surfactant in combination with similarly charged alumina nanoparticles at concentrations as low as 10-5 M and 10-4 wt.%, respectively. The surfactant molecules adsorb... Read More about Novel oil-in-water emulsions stabilised by ionic surfactant and similarly charged nanoparticles at very low concentrations.

Phase inversion of colored Pickering emulsions stabilized by organic pigment particle mixtures (2018)
Journal Article
Binks, B. P., & Olusanya, S. O. (2018). Phase inversion of colored Pickering emulsions stabilized by organic pigment particle mixtures. Langmuir : the ACS journal of surfaces and colloids, 34(17), 5040-5051. https://doi.org/10.1021/acs.langmuir.8b00715

Pickering emulsions stabilized by a mixture of coloured organic pigment particles of different hydrophobicity have been investigated at equal oil:water ratio and a fixed overall particle concentration by several complementary methods. Transitional ph... Read More about Phase inversion of colored Pickering emulsions stabilized by organic pigment particle mixtures.

Heterogeneous Pd catalysts as emulsifiers in Pickering emulsions for integrated multistep synthesis in flow chemistry (2018)
Journal Article
Hiebler, K., Lichtenegger, G. J., Maier, M. C., Park, E. S., Gonzales-Groom, R., Binks, B. P., & Gruber-Woelfler, H. (2018). Heterogeneous Pd catalysts as emulsifiers in Pickering emulsions for integrated multistep synthesis in flow chemistry. Beilstein Journal of Organic Chemistry, 14, 648-658. https://doi.org/10.3762/bjoc.14.52

Within the “Compartmentalised Smart Factory” approach of the ONE-FLOW project the implementation of different catalysts in “compartments” provided by Pickering emulsions and their application in continuous flow is targeted. We present here the develo... Read More about Heterogeneous Pd catalysts as emulsifiers in Pickering emulsions for integrated multistep synthesis in flow chemistry.

Surface-active hollow titanosilicate particles as a Pickering interfacial catalyst for liquid-phase alkene epoxidation reactions (2017)
Journal Article
Lv, G., Wang, F., Zhang, X., & Binks, B. P. (2018). Surface-active hollow titanosilicate particles as a Pickering interfacial catalyst for liquid-phase alkene epoxidation reactions. Langmuir : the ACS journal of surfaces and colloids, 34(1), 302-310. https://doi.org/10.1021/acs.langmuir.7b03633

Design of catalyst particles bearing excellent catalytic activity and suitable surface wettability is the key to the successful application of Pickering interfacial catalysis. In this study, the epoxidation of 1-hexene and cyclohexene with aqueous hy... Read More about Surface-active hollow titanosilicate particles as a Pickering interfacial catalyst for liquid-phase alkene epoxidation reactions.

Emulsion stabilisation by complexes of oppositely charged synthetic polyelectrolytes (2017)
Journal Article
Bago Rodriguez, A. M., Binks, B. P., & Sekine, T. (2018). Emulsion stabilisation by complexes of oppositely charged synthetic polyelectrolytes. Soft matter, 14(2), 239-254. https://doi.org/10.1039/c7sm01845b

We investigate the possibility of stabilising oil-water emulsions from the polyelectrolyte complexes (PEC) obtained in mixtures of a strong cationic polyelectrolyte (poly(diallyldimethylammonium chloride), PDADMAC) and a weak anionic one (poly(acryli... Read More about Emulsion stabilisation by complexes of oppositely charged synthetic polyelectrolytes.

Ionic liquid droplet micro-reactor for catalysis reactions not at equilibrium (2017)
Journal Article
Zhang, M., Ettelaie, R., Yan, T., Zhang, S., Cheng, F., Binks, B. P., & Yang, H. (2017). Ionic liquid droplet micro-reactor for catalysis reactions not at equilibrium. Journal of the American Chemical Society, 139(48), 17387-17396. https://doi.org/10.1021/jacs.7b07731

We develop a novel strategy to more effectively and controllably process continuous enzymatic or homogeneous catalysis reactions based on non-aqueous Pickering emulsions. A key element of this strategy is “bottom-up” construction of a macroscale cont... Read More about Ionic liquid droplet micro-reactor for catalysis reactions not at equilibrium.

Superposition of translational and rotational motions under self-propulsion of liquid marbles filled by aqueous solutions of camphor (2017)
Journal Article
Bormashenko, E. Y., Frenkel, M., Bormashenko, Y., Chaniel, G., Valtsifer, V. A., & Binks, B. P. (2017). Superposition of translational and rotational motions under self-propulsion of liquid marbles filled by aqueous solutions of camphor. Langmuir : the ACS journal of surfaces and colloids, 33(46), 13234-13241. https://doi.org/10.1021/acs.langmuir.7b03356

Self-locomotion of liquid marbles, coated with lycopodium or fumed fluorosilica powder, filled with a saturated aqueous solution of camphor and placed on a water/vapor interface is reported. Self-propelled marbles demonstrated a complicated motion, r... Read More about Superposition of translational and rotational motions under self-propulsion of liquid marbles filled by aqueous solutions of camphor.

Converting metal-organic framework particles from hydrophilic to hydrophobic by an interfacial assembling route (2017)
Journal Article
Zhang, F., Sang, X., Tan, X., Liu, C., Zhang, J., Luo, T., Liu, L., Han, B., Yang, G., & Binks, B. P. (2017). Converting metal-organic framework particles from hydrophilic to hydrophobic by an interfacial assembling route. Langmuir : the ACS journal of surfaces and colloids, 33(43), 12427-12433. https://doi.org/10.1021/acs.langmuir.7b02365

Here we propose to modify the hydrophilicity of metal-organic framework (MOF) particles by an interfacial assembling route, which is based on the surface-active nature of MOF particles. It was found that hydrophilic UiO-66-NH₂ particles can be conver... Read More about Converting metal-organic framework particles from hydrophilic to hydrophobic by an interfacial assembling route.

Modeling the interfacial energy of surfactant-free amphiphilic Janus nanoparticles from phase inversion in Pickering emulsions (2017)
Journal Article
Wu, D., Binks, B. P., & Honciuc, A. (2018). Modeling the interfacial energy of surfactant-free amphiphilic Janus nanoparticles from phase inversion in Pickering emulsions. Langmuir : the ACS journal of surfaces and colloids, 34(3), 1225-1233. https://doi.org/10.1021/acs.langmuir.7b02331

Determining the interfacial energy of nanoparticles is very challenging via traditional methods that first require measuring the contact angle of several liquids of a sessile drop on pellets or capillary rise in powder beds. In this work, we propose... Read More about Modeling the interfacial energy of surfactant-free amphiphilic Janus nanoparticles from phase inversion in Pickering emulsions.

Use of Mg(OH)2 particles as stabilisers in Pickering emulsions (2017)
Thesis
Turner, D. J. Use of Mg(OH)2 particles as stabilisers in Pickering emulsions. (Thesis). University of Hull. https://hull-repository.worktribe.com/output/4223312

Twenty-six different samples of magnesium hydroxide particles were formed from various reactants and under varied reaction conditions. The morphologies of the different magnesium hydroxide samples were assessed via SEM and TEM and their zeta potentia... Read More about Use of Mg(OH)2 particles as stabilisers in Pickering emulsions.

Fabrication of hierarchical macroporous biocompatible scaffolds by combining Pickering high internal phase emulsion templates with three-dimensional printing (2017)
Journal Article
Yang, T., Hu, Y., Wang, C., & Binks, B. P. (2017). Fabrication of hierarchical macroporous biocompatible scaffolds by combining Pickering high internal phase emulsion templates with three-dimensional printing. ACS Applied Materials & Interfaces, 9(27), 22950-22958. https://doi.org/10.1021/acsami.7b05012

Biocompatible and biodegradable porous scaffolds with adjustable pore structure have aroused increasing interest in bone tissue engineering. Here, we report a facile method to fabricate hierarchical macroporous biocompatible (HmPB) scaffolds by combi... Read More about Fabrication of hierarchical macroporous biocompatible scaffolds by combining Pickering high internal phase emulsion templates with three-dimensional printing.

Polymer-protein conjugate particles with biocatalytic activity for stabilization of water-in-water emulsions (2017)
Journal Article
Xue, L.-H., Xie, C.-Y., Meng, S.-X., Bai, R.-X., Yang, X., Wang, Y., Wang, S., Binks, B. P., Guo, T., & Meng, T. (2017). Polymer-protein conjugate particles with biocatalytic activity for stabilization of water-in-water emulsions. ACS Macro Letters, 6(7), 679-683. https://doi.org/10.1021/acsmacrolett.7b00294

Water-in-water (w/w) emulsions are attractive micro-compartmentalized platforms due to their outstanding biocom-patibility. To address the main disadvantage of poor stability that hampers their practical application, here we report a novel type of po... Read More about Polymer-protein conjugate particles with biocatalytic activity for stabilization of water-in-water emulsions.

CO₂/N₂ triggered switchable Pickering emulsions stabilized by alumina nanoparticles in combination with a conventional anionic surfactant (2017)
Journal Article
Xu, M., Zhang, W., Pei, X., Jiang, J., Cui, Z., & Binks, B. P. (2017). CO₂/N₂ triggered switchable Pickering emulsions stabilized by alumina nanoparticles in combination with a conventional anionic surfactant. RSC advances, 7(47), 29742-29751. https://doi.org/10.1039/c7ra03722h

Stable n-decane-in-water Pickering emulsions were prepared using positively charged alumina nanoparticles in combination with a trace amount of the anionic surfactant sodium dodecyl sulfate (SDS) as stabilizer. Particles were hydrophobized in situ by... Read More about CO₂/N₂ triggered switchable Pickering emulsions stabilized by alumina nanoparticles in combination with a conventional anionic surfactant.

Thermoresponsive Pickering emulsions stabilized by silica nanoparticles in combination with alkyl polyoxyethylene ether nonionic surfactant (2017)
Journal Article
Zhu, Y., Fu, T., Liu, K., Lin, Q., Pei, X., Jiang, J., Cui, Z., & Binks, B. P. (2017). Thermoresponsive Pickering emulsions stabilized by silica nanoparticles in combination with alkyl polyoxyethylene ether nonionic surfactant. Langmuir : the ACS journal of surfaces and colloids, 33(23), 5724-5733. https://doi.org/10.1021/acs.langmuir.7b00273

We put forward a simple protocol to prepare thermo-responsive Pickering emulsions. Using hydrophilic silica nanoparticles in combination with a low concentration of alkyl polyoxyethylene monododecyl ether (C12En) nonionic surfactant as emulsifier, oi... Read More about Thermoresponsive Pickering emulsions stabilized by silica nanoparticles in combination with alkyl polyoxyethylene ether nonionic surfactant.

Collodial particles at a range of fluid-fluid particles (2017)
Journal Article
Binks, B. P. (2017). Collodial particles at a range of fluid-fluid particles. Langmuir : the ACS journal of surfaces and colloids, 33(28), 6947-6963. https://doi.org/10.1021/acs.langmuir.7b00860

The study of solid particles residing at fluid-fluid interfaces has become an established area in surface and colloid science recently experiencing a renaissance since around 2000. Particles at interfaces arise in many industrial products and process... Read More about Collodial particles at a range of fluid-fluid particles.

Stability of clay particle-coated microbubbles in alkanes against dissolution induced by heating (2017)
Journal Article
Achakulwisut, K., Tam, C., Huerre, A., Sammouti, R., Binks, B. P., & Garbin, V. (2017). Stability of clay particle-coated microbubbles in alkanes against dissolution induced by heating. Langmuir : the ACS journal of surfaces and colloids, 33(15), 3809-3817. https://doi.org/10.1021/acs.langmuir.7b00429

We investigated the dissolution and morphological dynamics of air bubbles in alkanes stabilized by fluorinated colloidal clay particles when subjected to temperature changes. A quasi-steady model for bubble dissolution with time-dependent temperature... Read More about Stability of clay particle-coated microbubbles in alkanes against dissolution induced by heating.

Spectrophotometry of thin films of light absorbing particles (2017)
Journal Article
Binks, B. P., Fletcher, P. D., Johnson, A. J., Marinopoulos, I., Crowther, J. M., & Thompson, M. A. (2017). Spectrophotometry of thin films of light absorbing particles. Langmuir : the ACS journal of surfaces and colloids, 33(15), 3720-3730. https://doi.org/10.1021/acs.langmuir.6b04443

Thin films of dispersions of light absorbing solid particles or emulsions containing a light absorbing solute all have a non-uniform distribution of light absorbing species throughout the sample volume. This results in non-uniform light absorption ov... Read More about Spectrophotometry of thin films of light absorbing particles.

Ultra-stable self-foaming oils (2017)
Journal Article
Binks, B. P., & Marinopoulos, I. (2017). Ultra-stable self-foaming oils. Food Research International, 95, 28-37. https://doi.org/10.1016/j.foodres.2017.02.020

This paper is concerned with the foaming of a range of fats in the absence of added foaming agent/emulsifier. By controlling the temperature on warming from the solid or cooling from the melt, crystals of high melting triglycerides form in a continuo... Read More about Ultra-stable self-foaming oils.

Smart worm-like micelles responsive to CO₂/N₂ and light dual stimuli (2017)
Journal Article
Jiang, J., Wang, G., Ma, Y., Cui, Z., & Binks, B. P. (2017). Smart worm-like micelles responsive to CO₂/N₂ and light dual stimuli. Soft matter, 13(15), 2727-2732. https://doi.org/10.1039/C7SM00185A

CO₂/N₂ and light dual stimuli-reponsive worm-like micelles (WLMs) were obtained by addition of a relatively small amount of a switchable surfactant, 4-butyl-4´-(4-N,N-dimethylhexyloxy-amine) azobenzene bicarbonate (AZO-B6-CO₂), sensitive to the same... Read More about Smart worm-like micelles responsive to CO₂/N₂ and light dual stimuli.

pH-responsive Pickering emulsions stabilized by silica nanoparticles in combination with a conventional zwitterionic surfactant (2017)
Journal Article
Liu, K., Jiang, J., Cui, Z., & Binks, B. P. (2017). pH-responsive Pickering emulsions stabilized by silica nanoparticles in combination with a conventional zwitterionic surfactant. Langmuir : the ACS journal of surfaces and colloids, 33(9), 2296-2305. https://doi.org/10.1021/acs.langmuir.6b04459

pH-responsive oil-in-water Pickering emulsions were prepared simply by using negatively charged silica nanoparticles in combination with a trace amount of a zwitterionic carboxyl betaine surfactant as stabilizer. Emulsions are stable to coalescence a... Read More about pH-responsive Pickering emulsions stabilized by silica nanoparticles in combination with a conventional zwitterionic surfactant.